The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Dendrite‐Free Zinc Deposition Induced by Tin‐Modified Multifunctional 3D Host for Stable Zinc‐Based Flow Battery
Abstract
Zinc (Zn) plating/stripping is a promising anodic electrochemical reaction for aqueous batteries because of its high safety, low cost, two electron transfer, and rapid reaction kinetics. However, the notorious dendrite growth of Zn has become one of the biggest obstacles hindering its further commercialization. A multifunctional binder‐free tin (Sn)‐modified 3D carbon felt anodic host (SH) is constructed for aqueous zinc‐based flow batteries (ZFB) via a facile and scalable strategy. Compared with the pristine carbon felt host (PH), the as‐fabricated SH affords more robust Zn nucleation sites, lower hydrogen evolution reaction potential and lower nucleation overpotential of Zn and thus better induces uniform Zn plating/stripping with very high Coulombic efficiency (CE). Based on such an SH, a symmetrical flow battery exhibits superior CE (290 cycles with average CE of 99.4%) and a zinc–bromine flow battery demonstrates a longer cycle life (142 cycles with average CE of 97.2%), much better than pristine PH. This is a simple, novel, and effective way to suppress Zn dendrites and improve the performance of ZFBs.
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Cites
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Cited by
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Recent Progress on Zn Anodes for Advanced Aqueous Zinc‐Ion Batteries
Nie, C., Wang, G., Wang, D., Wang, M., Gao, X., Bai, Z., Wang, N., Yang, J., Xing, Z., & Dou, S. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202300606 · Cited by 561
Design of a Solid Electrolyte Interphase for Aqueous Zn Batteries
Li, D., Cao, L., Deng, T., Liu, S., & Wang, C. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202103390 · Cited by 466
Zinc dendrite growth and inhibition strategies
Zuo, Y., Wang, K., Pei, P., Wei, M., Liu, X., Xiao, Y., & Zhang, P. (2021) · Materials Today Energy · doi:10.1016/j.mtener.2021.100692 · Cited by 409
Issues and solutions toward zinc anode in aqueous zinc‐ion batteries: A mini review
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Metadata
- Authors
- Yin, Y., Wang, S., Zhang, Q., Song, Y., Chang, N., Pan, Y., Zhang, H., & Li, X.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2019-12-18
- Volume
- 32
- Issue
- 6
- Pages
- e1906803-e1906803
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2996593125
- Cited by
- 429
- References
- 34
- FWCI
- 17.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yin, Y., Wang, S., Zhang, Q., Song, Y., Chang, N., Pan, Y., Zhang, H., & Li, X. (2020). Dendrite‐Free Zinc Deposition Induced by Tin‐Modified Multifunctional 3D Host for Stable Zinc‐Based Flow Battery. Advanced Materials. https://doi.org/10.1002/adma.201906803
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