The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
RhSe2: A Superior 3D Electrocatalyst with Multiple Active Facets for Hydrogen Evolution Reaction in Both Acid and Alkaline Solutions
Abstract
Layered 2D materials are a vital class of electrocatalys for the hydrogen evolution reaction (HER), due to their large area, excellent activity, and facile fabrication. Theoretical caculations domenstrate, however, that only the edges of the 2D nanosheets act as active sites, while the much larger basal plane exhibits passive activity. Here, from a distinguishing perspective, RhSe 2 is reported as a “3D” electrocatalyst for HER with top‐class activity, synthesized by a facile solid‐state method. Superior to 2D materials, multiple crystal facets of RhSe 2 exhibit near‐zero free energy change of hydrogen adsorption (Δ GH), which guarantees high performance in most common morphologies. Density functional theory calculations reveal that the low‐coordinated Rh atoms act as the active sites in acid, which enables the modified Kubas‐mediated pathway, while the Se atoms act as the active sites in an alkaline medium. The overpotentials of HER activity of RhSe 2 are measured to be 49.9 and 81.6 mV at 10 mA cm–2 in acid and alkaline solutions, respectively. This work paves the way to new transition metal chalcogenide catalysts.
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2D transition metal dichalcogenides
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Self‐Supported Transition‐Metal‐Based Electrocatalysts for Hydrogen and Oxygen Evolution
Sun, H., Yan, Z., Liu, F., Xu, W., Cheng, F., & Chen, J. (2020) · Advanced Materials · doi:10.1002/adma.201806326 · Cited by 1,734
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Nanoarchitectonics for Transition‐Metal‐Sulfide‐Based Electrocatalysts for Water Splitting
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Self-citationUltrathin metal-organic framework array for efficient electrocatalytic water splitting
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High Electrocatalytic Hydrogen Evolution Activity of an Anomalous Ruthenium Catalyst
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Emerging Dual‐Atomic‐Site Catalysts for Efficient Energy Catalysis
Zhang, W., Chao, Y., Zhang, W., Zhou, J., Lv, F., Wang, K., Lin, F., Luo, H., Li, J., Tong, M., et al. (2021) · Advanced Materials · doi:10.1002/adma.202102576 · Cited by 528
Engineering Ruthenium-Based Electrocatalysts for Effective Hydrogen Evolution Reaction
Yang, Y., Yu, Y., Li, J., Chen, Q., Du, Y., Rao, P., Li, R., Jia, C., Kang, Z., Deng, P., et al. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00679-3 · Cited by 313
Chen, D., Lu, R., Yu, R., Dai, Y., Zhao, H., Wu, D., Wang, P., Zhu, J., Pu, Z., Chen, L., et al. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202208642 · Cited by 312
Li, Y., Wang, W., Cheng, M., Feng, Y., Han, X., Qian, Q., Zhu, Y., & Zhang, G. (2023) · Advanced Materials · doi:10.1002/adma.202206351 · Cited by 282
Shen, S., Hu, Z., Zhang, H., Song, K., Wang, Z., Lin, Z., Zhang, Q., Gu, L., & Zhong, W. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202206460 · Cited by 140
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Metadata
- Authors
- Zhong, W., Xiao, B., Lin, Z., Wang, Z., Huang, L., Shen, S., Zhang, Q., & Gu, L.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2021-01-29
- Volume
- 33
- Issue
- 9
- Pages
- e2007894-e2007894
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W3125426723
- Cited by
- 258
- References
- 39
- FWCI
- 10.09
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhong, W., Xiao, B., Lin, Z., Wang, Z., Huang, L., Shen, S., Zhang, Q., & Gu, L. (2021). RhSe2: A Superior 3D Electrocatalyst with Multiple Active Facets for Hydrogen Evolution Reaction in Both Acid and Alkaline Solutions. Advanced Materials. https://doi.org/10.1002/adma.202007894
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