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The Design of Fused Amine/Carbonyl System for Efficient Thermally Activated Delayed Fluorescence: Novel Multiple Resonance Core and Electron Acceptor

Yuan, Yi, Tang, Xun, Du, Xiao‐Yang, Hu, Yun, Yu, You‐Jun, Jiang, Zuo‐Quan, Liao, Liang‐Sheng, Lee, Shuit‐Tong·2019·Advanced Optical Materials

Abstract

Multiple resonances induced thermally activated delayed fluorescence (MR‐TADF) has great advantages in high color purity display. Up to now, current MR‐TADF emitters are only based on the boron‐nitrogen‐containing fragment. Reported herein is a novel class of MR‐TADF emitter, quinolino[3,2,1‐de]acridine‐5,9‐dione (QAO), realized by the opposite resonance effect of the carbonyl and the nitrogen atoms, which is also the smallest TADF emitter reported so far. The QAO‐based pure blue organic light‐emitting diode achieves a maximum external quantum efficiency (EQE max) of 19.4% with a small full width at half maximum of 39 nm. Moreover, tert‐butyl modified QAO can be employed as an efficient electron acceptor to construct an efficient yellow‐green evaporation and solution process feasible TADF emitter, 7‐(tert‐butyl)‐3,11‐bis(9,9‐dimethylacridin‐10(9 H)‐yl)quinolino[3,2,1‐de]acridine‐5,9‐dione (QAO‐DAd), with significantly improved performance as compared to the previous flexible diketone‐based emitters.

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Metadata

Authors
Yuan, Y., Tang, X., Du, X., Hu, Y., Yu, Y., Jiang, Z., Liao, L., & Lee, S.
Venue
Advanced Optical Materials
Publisher
Wiley
Published
2019-01-08
Volume
7
Issue
7
ISSN
2195-1071 (ISSN-L)
OpenAlex
W2910102247
Cited by
404
References
29
FWCI
12.07
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: The Design of Fused Amine/Carbonyl System for Efficient Thermally Activated Delayed Fluorescence: Novel Multiple Resonance Core and Electron Acceptor. https://app.cochat.ai/papers/10.1002/adom.201801536
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Yuan, Y., Tang, X., Du, X., Hu, Y., Yu, Y., Jiang, Z., Liao, L., & Lee, S. (2019). The Design of Fused Amine/Carbonyl System for Efficient Thermally Activated Delayed Fluorescence: Novel Multiple Resonance Core and Electron Acceptor. Advanced Optical Materials. https://doi.org/10.1002/adom.201801536

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