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Rationally Designed Hierarchically Structured Tungsten Nitride and Nitrogen‐Rich Graphene‐Like Carbon Nanocomposite as Efficient Hydrogen Evolution Electrocatalyst

Open access
Zhu, Yanping, Chen, Gao, Zhong, Yijun, Zhou, Wei, Shao, Zongping·2018·Advanced Science

Abstract

Practical application of hydrogen production from water splitting relies strongly on the development of low‐cost and high‐performance electrocatalysts for hydrogen evolution reaction (HER). The previous researches mainly focused on transition metal nitrides as HER catalysts due to their electrical conductivity and corrosion stability under acidic electrolyte, while tungsten nitrides have reported poorer activity for HER. Here the activity of tungsten nitride is optimized through rational design of a tungsten nitride–carbon composite. More specifically, tungsten nitride (WNx) coupled with nitrogen‐rich porous graphene‐like carbon is prepared through a low‐cost ion‐exchange/molten‐salt strategy. Benefiting from the nanostructured WNx, the highly porous structure and rich nitrogen dopant (9.5 at%) of the carbon phase with high percentage of pyridinic‐N (54.3%), and more importantly, their synergistic effect, the composite catalyst displays remarkably high catalytic activity while maintaining good stability. This work highlights a powerful way to design more efficient metal–carbon composites catalysts for HER.

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Metadata

Authors
Zhu, Y., Chen, G., Zhong, Y., Zhou, W., & Shao, Z.
Venue
Advanced Science
Publisher
Wiley
Published
2017-12-08
Volume
5
Issue
2
Pages
1700603-1700603
ISSN
2198-3844 (ISSN-L)
OpenAlex
W2772059695
Cited by
165
References
4
FWCI
4.98
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Rationally Designed Hierarchically Structured Tungsten Nitride and Nitrogen‐Rich Graphene‐Like Carbon Nanocomposite as Efficient Hydrogen Evolution Electrocatalyst. https://app.cochat.ai/papers/10.1002/advs.201700603
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Zhu, Y., Chen, G., Zhong, Y., Zhou, W., & Shao, Z. (2018). Rationally Designed Hierarchically Structured Tungsten Nitride and Nitrogen‐Rich Graphene‐Like Carbon Nanocomposite as Efficient Hydrogen Evolution Electrocatalyst. Advanced Science. https://doi.org/10.1002/advs.201700603

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