The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Sub‐50 nm Iron–Nitrogen‐Doped Hollow Carbon Sphere‐Encapsulated Iron Carbide Nanoparticles as Efficient Oxygen Reduction Catalysts
Open accessAbstract
Sub‐50 nm iron–nitrogen‐doped hollow carbon sphere‐encapsulated iron carbide nanoparticles (Fe 3 C‐Fe,N/C) are synthesized by using a triblock copolymer of poly(styrene‐b‐2‐vinylpyridine‐b‐ethylene oxide) as a soft template. Their typical features, including a large surface area (879.5 m 2 g−1), small hollow size (≈16 nm), and nitrogen‐doped mesoporous carbon shell, and encapsulated Fe 3 C nanoparticles generate a highly active oxygen reduction reaction (ORR) performance. Fe 3 C‐Fe,N/C hollow spheres exhibit an ORR performance comparable to that of commercially available 20 wt% Pt/C in alkaline electrolyte, with a similar half‐wave potential, an electron transfer number close to 4, and lower H 2 O 2 yield of less than 5%. It also shows noticeable ORR catalytic activity under acidic conditions, with a high half‐wave potential of 0.714 V, which is only 59 mV lower than that of 20 wt% Pt/C. Moreover, Fe 3 C‐Fe,N/C has remarkable long‐term durability and tolerance to methanol poisoning, exceeding Pt/C regardless of the electrolyte.
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Cites
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
Wu, G., More, K. L., Johnston, C. M., & Zelenay, P. (2011) · Science · doi:10.1126/science.1200832 · Cited by 3,984
Mesoporous carbon materials: Synthesis and modification
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High oxygen-reduction activity and durability of nitrogen-doped graphene
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Self-citationYang, S., Feng, X., Wang, X., & Müllen, K. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201100170 · Cited by 1,109
Molecular-based design and emerging applications of nanoporous carbon spheres
Liu, J., Wickramaratne, N. P., Qiao, S. Z., & Jaroniec, M. (2015) · Nature Materials · doi:10.1038/nmat4317 · Cited by 954
Wang, Q., Shang, L., Shi, R., Zhang, X., Zhao, Y., Waterhouse, G. I. N., Wu, L., Tung, C., & Zhang, T. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700467 · Cited by 508
Cited by
Park, J., Lee, S., Kim, H., Cho, A., Kim, S., Ye, Y., Han, J. W., Lee, H., Jang, J. H., & Lee, J. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201908122 · Cited by 480
Metal‐Nitrogen‐Doped Carbon Materials as Highly Efficient Catalysts: Progress and Rational Design
Shi, Z., Yang, W., Gu, Y., Liao, T., & Sun, Z. (2020) · Advanced Science · doi:10.1002/advs.202001069 · Cited by 470
Ultrathinning Nickel Sulfide with Modulated Electron Density for Efficient Water Splitting
Fei, B., Chen, Z., Liu, J., Xu, H., Yan, X., Qing, H., Chen, M., & Wu, R. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001963 · Cited by 372
Ultra-dense carbon defects as highly active sites for oxygen reduction catalysis
Wu, Q., Jia, Y., Liu, Q., Mao, X., Guo, Q., Yan, X., Zhao, J., Liu, F., Du, A., & Yao, X. (2022) · Chem · doi:10.1016/j.chempr.2022.06.013 · Cited by 233
Wu, X., Ni, C., Man, J., Shen, X., Cui, S., & Chen, X. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.140293 · Cited by 47
Metadata
- Authors
- Tan, H., Li, Y., Kim, J., Takei, T., Wang, Z., Xu, X., Wang, J., Bando, Y., Kang, Y., Tang, J., & Yamauchi, Y.
- Venue
- Advanced Science
- Publisher
- Wiley
- Published
- 2018-05-12
- Volume
- 5
- Issue
- 7
- Pages
- 1800120-1800120
- ISSN
- 2198-3844 (ISSN-L)
- OpenAlex
- W2799850584
- Cited by
- 220
- References
- 6
- FWCI
- 7.41
- Type
- journal article
- Language
- en
- Open access
- gold
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- Tan, H., Li, Y., Kim, J., Takei, T., Wang, Z., Xu, X., Wang, J., Bando, Y., Kang, Y., Tang, J., & Yamauchi, Y. (2018). Sub‐50 nm Iron–Nitrogen‐Doped Hollow Carbon Sphere‐Encapsulated Iron Carbide Nanoparticles as Efficient Oxygen Reduction Catalysts. Advanced Science. https://doi.org/10.1002/advs.201800120
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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