Cited by 719Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

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Porous electrode materials for lithium-ion batteries–how to prepare them and what makes them special

Vu, Anh, Qian, Yuqiang, Stein, Andreas·2012·Advanced Energy Materials

DOI 10.1002/aenm.201200320

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Abstract

Abstract Numerous benefits of porous electrode materials for lithium ion batteries (LIBs) have been demonstrated, including examples of higher rate capabilities, better cycle lives, and sometimes greater gravimetric capacities at a given rate compared to nonporous bulk materials. These properties promise advantages of porous electrode materials for LIBs in electric and hybrid electric vehicles, portable electronic devices, and stationary electrical energy storage. This review highlights methods of synthesizing porous electrode materials by templating and template‐free methods and discusses how the structural features of porous electrodes influence their electrochemical properties. A section on electrochemical properties of porous electrodes provides examples that illustrate the influence of pore and wall architecture and interconnectivity, surface area, particle morphology, and nanocomposite formation on the utilization of the electrode materials, specific capacities, rate capabilities, and structural stability during lithiation and delithiation processes. Recent applications of porous solids as components for three‐dimensionally interpenetrating battery architectures are also described.

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Authors: Vu, A., Qian, Y., & Stein, A.
Affiliations: University of Minnesota (US)
Corresponding author: Stein, Andreas
ORCID: Vu, Anh
Qian, Yuqiang
Stein, Andreas
Venue: Advanced Energy Materials
Publisher: Wiley
Published: 2012-08-13
Volume: 2
Issue: 9
Pages: 1056-1085
ISSN: 1614-6832 (ISSN-L)
1614-6840
DOI: 10.1002/aenm.201200320
OpenAlex: W2138936929
Cited by: 719
References: 251
Citations by year: 2026: 22 · 2025: 44 · 2024: 50 · 2023: 41 · 2022: 39 · 2021: 35 · 2020: 47 · 2019: 41 · 2018: 51 · 2017: 83 · 2016: 66 · 2015: 86 · 2014: 72 · 2013: 38 · 2012: 2
FWCI: 40.46
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Advanced Energy Materials (publishedVersion)
Topics: Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
Keywords: porous electrode materials, lithium-ion batteries, templating, template-free synthesis, pore structure, surface area, particle morphology, nanocomposites, rate capability, cycle life, gravimetric capacity

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Porous electrode materials for lithium-ion batteries–how to prepare them and what makes them special

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