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Porous electrode materials for lithium-ion batteries–how to prepare them and what makes them special
Abstract
Abstract Numerous benefits of porous electrode materials for lithium ion batteries (LIBs) have been demonstrated, including examples of higher rate capabilities, better cycle lives, and sometimes greater gravimetric capacities at a given rate compared to nonporous bulk materials. These properties promise advantages of porous electrode materials for LIBs in electric and hybrid electric vehicles, portable electronic devices, and stationary electrical energy storage. This review highlights methods of synthesizing porous electrode materials by templating and template‐free methods and discusses how the structural features of porous electrodes influence their electrochemical properties. A section on electrochemical properties of porous electrodes provides examples that illustrate the influence of pore and wall architecture and interconnectivity, surface area, particle morphology, and nanocomposite formation on the utilization of the electrode materials, specific capacities, rate capabilities, and structural stability during lithiation and delithiation processes. Recent applications of porous solids as components for three‐dimensionally interpenetrating battery architectures are also described.
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“With these unique features, porous materials present great value for applications in energy conversion and storage [132,133,134,135], catalysis [136], drug delivery [137], gas capture [138,139], and water purification [140,141].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [134]
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Metadata
- Authors
- Vu, A., Qian, Y., & Stein, A.
- Affiliations
- University of Minnesota (US)
- Corresponding author
- Stein, Andreas
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2012-08-13
- Volume
- 2
- Issue
- 9
- Pages
- 1056-1085
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2138936929
- Cited by
- 719
- References
- 251
- Citations by year
- 2026: 22 · 2025: 44 · 2024: 50 · 2023: 41 · 2022: 39 · 2021: 35 · 2020: 47 · 2019: 41 · 2018: 51 · 2017: 83 · 2016: 66 · 2015: 86 · 2014: 72 · 2013: 38 · 2012: 2
- FWCI
- 40.46
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Energy Materials (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- porous electrode materials, lithium-ion batteries, templating, template-free synthesis, pore structure, surface area, particle morphology, nanocomposites, rate capability, cycle life, gravimetric capacity
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