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Supercapacitor Electrodes Obtained by Directly Bonding 2D MoS2 on Reduced Graphene Oxide

da Silveira Firmiano, Edney Geraldo, Rabelo, Adriano C., Dalmaschio, Cleocir J., Pinheiro, Antonio N., Pereira, Ernesto C., Schreiner, Wido H., Leite, Edson Robeto·2014·Advanced Energy Materials

Abstract

Layered molybdenum disulfide (MoS 2) is deposited by microwave heating on a reduced graphene oxide (RGO). Three concentrations of MoS 2 are loaded on RGO, and the structure and morphology are characterized. The first layers of MoS 2 are detected as being directly bonded with the oxygen of the RGO by covalent chemical bonds (Mo‐O‐C). Electrochemical characterizations indicate that this electroactive material can be cycled reversibly between 0.25 and 0.8 V in 1 m HClO 4 solution for hybrids with low concentrations of MoS 2 layers (LCMoS 2/RGO) and between 0.25 and 0.65 V for medium (MCMoS 2/RGO) and high concentrations (HCMoS 2/RGO) of MoS 2 layers on graphene. The specific capacitance measured values at 10 mV s−1 are 128, 265, and 148 Fg−1 for the MoS 2/RGO with low, medium, and high concentrations of MoS 2, respectively, and the calculated energy density is 63 W h kg−1 for the LCMoS 2/RGO hybrid. This supercapacitor electrode also exhibits superior cyclic stability with 92% of the specific capacitance retained after 1000 cycles.

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Metadata

Authors
da Silveira Firmiano, E. G., Rabelo, A. C., Dalmaschio, C. J., Pinheiro, A. N., Pereira, E. C., Schreiner, W. H., & Leite, E. R.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2013-11-18
Volume
4
Issue
6
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W2137977053
Cited by
529
References
4
FWCI
12.24
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Supercapacitor Electrodes Obtained by Directly Bonding 2D MoS2 on Reduced Graphene Oxide. https://app.cochat.ai/papers/10.1002/aenm.201301380
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da Silveira Firmiano, E. G., Rabelo, A. C., Dalmaschio, C. J., Pinheiro, A. N., Pereira, E. C., Schreiner, W. H., & Leite, E. R. (2014). Supercapacitor Electrodes Obtained by Directly Bonding 2D MoS2 on Reduced Graphene Oxide. Advanced Energy Materials. https://doi.org/10.1002/aenm.201301380

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