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Cited by 284

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Mechanistic Insights of Zn2+ Storage in Sodium Vanadates

Guo, Xun, Fang, Guozhao, Zhang, Wenyu, Zhou, Jiang, Shan, Lutong, Wang, Liangbing, Wang, Chao, Lin, Tianquan, Tang, Yan, Liang, Shuquan·2018·Advanced Energy Materials

Abstract

Rechargeable aqueous zinc‐ion batteries (ZIBs) with high safety and low‐cost are highly desirable for grid‐scale energy storage, yet the energy storage mechanisms in the current cathode materials are still complicated and unclear. Hence, several sodium vanadates with NaV 3 O 8‐type layered structure (e.g., Na 5 V 12 O 32 and HNaV 6 O 16·4H 2 O) and β‐Na 0.33 V 2 O 5‐type tunneled structure (e.g., Na 0.76 V 6 O 15) are constructed and the storage/release behaviors of Zn 2+ ions are deeply investigated in these two typical structures. It should be mentioned that the 2D layered Na 5 V 12 O 32 and HNaV 6 O 16·4H 2 O with more effective path for Zn 2+ diffusion exhibit higher ion diffusion coefficients than that of tunneled Na 0.76 V 6 O 15. As a result, Na 5 V 12 O 32 delivers higher capacity than that of Na 0.76 V 6 O 15, and a long‐term cyclic performance up to 2000 cycles at 4.0 A g−1 in spite of its capacity fading. This work provides a new perspective of Zn 2+ storage mechanism in aqueous ZIB systems.

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Metadata

Authors
Guo, X., Fang, G., Zhang, W., Zhou, J., Shan, L., Wang, L., Wang, C., Lin, T., Tang, Y., & Liang, S.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2018-08-09
Volume
8
Issue
27
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W2885927560
Cited by
284
References
34
FWCI
13.83
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Mechanistic Insights of Zn2+ Storage in Sodium Vanadates. https://app.cochat.ai/papers/10.1002/aenm.201801819
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Guo, X., Fang, G., Zhang, W., Zhou, J., Shan, L., Wang, L., Wang, C., Lin, T., Tang, Y., & Liang, S. (2018). Mechanistic Insights of Zn2+ Storage in Sodium Vanadates. Advanced Energy Materials. https://doi.org/10.1002/aenm.201801819

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