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Implanting Isolated Ru Atoms into Edge‐Rich Carbon Matrix for Efficient Electrocatalytic Hydrogen Evolution
Abstract
Although the maximized dispersion of metal atoms has been realized in the single‐atom catalysts, further improving the intrinsic activity of the catalysts is of vital importance. Here, the decoration of isolated Ru atoms into an edge‐rich carbon matrix is reported for the electrocatalytic hydrogen evolution reaction. The developed catalyst displays high catalytic performance with low overpotentials of 63 and 102 mV for achieving the current densities of 10 and 50 mA cm−2, respectively. Its mass activity is about 9.6 times higher than that of the commercial Pt/C‐20% catalyst at an overpotential of 100 mV. Experimental results and density functional theory calculations suggest that the edges in the carbon matrix enhance the local electric field at the Ru site and accelerate the reaction kinetics for the hydrogen evolution. The present work may provide insights into electrocatalytic behavior and guide the design of advanced electrocatalysts.
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“However, no characteristic peaks of Ru crystals can be observed in the XRD pattern because of the small particle size and low Ru content [29].”
From Nitrogen-doped graphene aerogel-supported ruthenium nanocrystals for pH-universal hydrogen evolution reaction (2022) · cites this paper as [29]
In the citing paper
“The dramatically enhanced activity from NCAG/Ru-1 to NCAG/ Ru-3 signifies the increasingly dominant contributions of the Ru single atom sites to the HER activity, as compared to the Ru nanoclusters [42,53].”
From Atomically dispersed ruthenium in carbon aerogels as effective catalysts for pH-universal hydrogen evolution reaction (2022) · cites this paper as [53]
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Metadata
- Authors
- Zhang, H., Zhou, W., Lu, X. F., Chen, T., & Lou, X. W. (.
- Affiliations
- Nanyang Technological University (SG)
- Tianjin University (CN)
- Chinese Academy of Sciences (CN)
- Corresponding author
- Lou, Xiong Wen (David)
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2020-05-05
- Volume
- 10
- Issue
- 23
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W3023294759
- Cited by
- 233
- References
- 42
- Citations by year
- 2026: 9 · 2025: 32 · 2024: 42 · 2023: 43 · 2022: 61 · 2021: 36 · 2020: 10
- FWCI
- 7.41
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Energy Materials (publishedVersion)
- DR-NTU (Nanyang Technological University) (submittedVersion)
- Funders
- Ministry of Education - Singapore (MOE2017‐T2‐2‐003)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- single-atom catalysts, electrocatalytic hydrogen evolution, carbon matrix, local electric field, reaction kinetics, mass activity, Pt/C comparison, catalyst design
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