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Cited by 429

The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.

Dual‐Sites Coordination Engineering of Single Atom Catalysts for Flexible Metal–Air Batteries

Yu, Deshuang, Ma, Yanchen, Hu, Feng, Lin, Chia‐Ching, Li, Linlin, Chen, Han‐Yi, Han, Xiaopeng, Peng, Shengjie·2021·Advanced Energy Materials

Abstract

Dual‐sites single atom catalysts hold promise for efficiently regulating multiple reaction processes and explicitly explaining the underlying mechanisms. However, delicate atomic engineering for dual‐site single atom catalysts remains a huge challenge. Herein, atomically dispersed Fe‐Ni single atoms embedded in a nitrogen‐doped carbon matrix (FeNi SAs/NC) are successfully developed with extraordinary activity for electrocatalytic oxygen reduction and evolution reactions (ORR/OER). The atomic FeNi SAs/NC catalyst displays high onset potential (0.98 V) and half‐wave potential (0.84 V) for the ORR, as well as, low overpotential of (270 mV) at 10 mA cm−2 for the OER. The density functional theory calculations indicate that the Fe site as the active center can facilitate the four‐electron reaction process, while Ni sites regulate the electronic structure of Fe sites and further reduce the energy barrier of the rate‐determining step. In addition, the nitrogen‐doped carbon matrix prevents the metal atoms from aggregation and corrosion, leading to the improvement of catalyst durability. As a proof of concept, flexible quasi‐solid‐state zinc– and aluminum–air batteries assembled with the FeNi SAs/NC catalyst exhibit superior peak power densities and discharging specific capacities outperforming the commercial Pt/C. This work provides rational guidance for the synthesis of bifunctional electrocatalysts in next‐generation energy devices for flexible consumer electronics.

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Metadata

Authors
Yu, D., Ma, Y., Hu, F., Lin, C., Li, L., Chen, H., Han, X., & Peng, S.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2021-06-19
Volume
11
Issue
30
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W3173682232
Cited by
429
References
45
FWCI
15.05
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Dual‐Sites Coordination Engineering of Single Atom Catalysts for Flexible Metal–Air Batteries. https://app.cochat.ai/papers/10.1002/aenm.202101242
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Yu, D., Ma, Y., Hu, F., Lin, C., Li, L., Chen, H., Han, X., & Peng, S. (2021). Dual‐Sites Coordination Engineering of Single Atom Catalysts for Flexible Metal–Air Batteries. Advanced Energy Materials. https://doi.org/10.1002/aenm.202101242

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