The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Ionic Exchange of Metal–Organic Frameworks to Access Single Nickel Sites for Efficient Electroreduction of CO2
Abstract
Single-atom catalysts often exhibit unexpected catalytic activity for many important chemical reactions because of their unique electronic and geometric structures with respect to their bulk counterparts. Herein we adopt metal–organic frameworks (MOFs) to assist the preparation of a catalyst containing single Ni sites for efficient electroreduction of CO 2 . The synthesis is based on ionic exchange between Zn nodes and adsorbed Ni ions within the cavities of the MOF. This single-atom catalyst exhibited an excellent turnover frequency for electroreduction of CO 2 (5273 h –1 ), with a Faradaic efficiency for CO production of over 71.9% and a current density of 10.48 mA cm –2 at an overpotential of 0.89 V. Our findings present some guidelines for the rational design and accurate modulation of nanostructured catalysts at the atomic scale.
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Cites
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Self-citationElectrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Fan, L., Liu, P. F., Yan, X., Gu, L., Yang, Z. Z., Yang, H. G., Qiu, S., & Yao, X. (2016) · Nature Communications · doi:10.1038/ncomms10667 · Cited by 748
Grain-Boundary-Dependent CO 2 Electroreduction Activity
Feng, X., Jiang, K., Fan, S., & Kanan, M. W. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5130513 · Cited by 694
Back, S., Lim, J., Kim, N.-Y., Kim, Y.-H., & Jung, Y. (2017) · Chemical Science · doi:10.1039/c6sc03911a · Cited by 542
Ma, M., Trześniewski, B. J., Xie, J., & Smith, W. A. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604654 · Cited by 530
Cited by
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239
Self-citationKibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331
Designing materials for electrochemical carbon dioxide recycling
Ross, M. B., De Luna, P., Li, Y., Dinh, C.-T., Kim, D., Yang, P., & Sargent, E. H. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0306-7 · Cited by 1,302
Self-citationElectrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887
Metadata
- Authors
- Zhao, C., Dai, X., Yao, T., Chen, W., Wang, X., Wang, J., Yang, J., Wei, S., Wu, Y., & Li, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-13
- Volume
- 139
- Issue
- 24
- Pages
- 8078-8081
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2624508105
- Cited by
- 1,365
- References
- 7
- FWCI
- 38.85
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhao, C., Dai, X., Yao, T., Chen, W., Wang, X., Wang, J., Yang, J., Wei, S., Wu, Y., & Li, Y. (2017). Ionic Exchange of Metal–Organic Frameworks to Access Single Nickel Sites for Efficient Electroreduction of CO2. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b02736
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