The DOI matches its Crossref record; 60 of the 60 references it cites were found in a registry or an index.
Enhancing the d/p‐Band Center Proximity with Amorphous‐Crystalline Interface Coupling for Boosted pH‐Robust Water Electrolysis
Abstract
Rationalizing non‐precious pH‐robust electrocatalysts is a crucial priority and required for multi‐scenario hydrogen production customization. Herein, an amorphous–crystalline CoBOx/NiSe heterostructure is theoretically profiled and constructed for efficient and pH‐robust water electrolysis. The crystalline lattice confinement induces a CoCo bond shortening and a B‐site delocalization on amorphous CoBOx, resulting in a decreased d‐p band center difference (Δε d‐p) toward the balanced intermediates adsorption/desorption. Accordingly, the CoBOx/NiSe heterostructure exhibits efficient and robust hydrogen/oxygen evolution reaction (HER/OER) catalytic activity in different electrolytes. Of particular note, it achieves ultralow overpotentials in both the beyond‐Pt HER (14.5 mV) and OER (229.1 mV) at 10 mA cm−2 under an alkaline electrolyte, and reaches an industrial‐level OER current density of 2 A cm−2. Water electrolysis is stably delivered with a low η 10 voltage of 1.48 V. The incorporation of such d‐p orbitals at the amorphous–crystalline interface puts forward new opportunities in rationally designing advanced non‐precious electrocatalysts for water electrolysis.
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Cites
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution
Grimaud, A., Diaz-Morales, O., Han, B., Hong, W. T., Lee, Y.-L., Giordano, L., Stoerzinger, K. A., Koper, M. T. M., & Shao-Horn, Y. (2017) · Nature Chemistry · doi:10.1038/nchem.2695 · Cited by 2,530
Sun, S., Zhou, X., Cong, B., Hong, W., & Chen, G. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01273 · Cited by 806
Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution
Tsai, C., Li, H., Park, S., Park, J., Han, H. S., Nørskov, J. K., Zheng, X., & Abild-Pedersen, F. (2017) · Nature Communications · doi:10.1038/ncomms15113 · Cited by 756
Hu, Q., Gao, K., Wang, X., Zheng, H., Cao, J., Mi, L., Huo, Q., Yang, H., Liu, J., & He, C. (2022) · Nature Communications · doi:10.1038/s41467-022-31660-2 · Cited by 744
Sulfur vacancy-rich MoS2 as a catalyst for the hydrogenation of CO2 to methanol
Hu, J., Yu, L., Deng, J., Wang, Y., Cheng, K., Ma, C., Zhang, Q., Wen, W., Yu, S., Pan, Y., et al. (2021) · Nature Catalysis · doi:10.1038/s41929-021-00584-3 · Cited by 742
Correlative operando microscopy of oxygen evolution electrocatalysts
Mefford, J. T., Akbashev, A. R., Kang, M., Bentley, C. L., Gent, W. E., Deng, H. D., Alsem, D. H., Yu, Y.-S., Salmon, N. J., Shapiro, D. A., et al. (2021) · Nature · doi:10.1038/s41586-021-03454-x · Cited by 699
Sun, Y., Xue, Z., Liu, Q., Jia, Y., Li, Y., Liu, K., Lin, Y., Liu, M., Li, G., & Su, C.-Y. (2021) · Nature Communications · doi:10.1038/s41467-021-21595-5 · Cited by 687
Sun, F., Qin, J., Wang, Z., Yu, M., Wu, X., Sun, X., & Qiu, J. (2021) · Nature Communications · doi:10.1038/s41467-021-24529-3 · Cited by 576
Shen, S., Wang, Z., Lin, Z., Song, K., Zhang, Q., Meng, F., Gu, L., & Zhong, W. (2022) · Advanced Materials · doi:10.1002/adma.202110631 · Cited by 575
Cited by
Wang, L., Ma, M., Zhang, C., Chang, H., Zhang, Y., Li, L., Chen, H., & Peng, S. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202317220 · Cited by 125
Self-citationLuo, N., Cai, A., Pei, J., Zeng, X., Wang, X., & Yao, N. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202425503 · Cited by 42
Liang, J., Wu, X., Ma, J., Huang, J., Wu, J., Zhong, R., Zou, Z., Hou, Y., Wang, Q., & Zheng, X. (2025) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.5c07668 · Cited by 5
Metadata
- Authors
- Liu, Y., Sakthivel, T., Hu, F., Tian, Y., Wu, D., Ang, E. H., Liu, H., Guo, S., Peng, S., & Dai, Z.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2023-01-26
- Volume
- 13
- Issue
- 11
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W4319790950
- Cited by
- 267
- References
- 60
- FWCI
- 12.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Liu, Y., Sakthivel, T., Hu, F., Tian, Y., Wu, D., Ang, E. H., Liu, H., Guo, S., Peng, S., & Dai, Z. (2023). Enhancing the d/p‐Band Center Proximity with Amorphous‐Crystalline Interface Coupling for Boosted pH‐Robust Water Electrolysis. Advanced Energy Materials. https://doi.org/10.1002/aenm.202203797
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