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New Catalytic Approaches in the Stereoselective Friedel–Crafts Alkylation Reaction
Abstract
After more than 125 years, the Friedel–Crafts alkylation is still one of the most studied and most utilized reactions in organic synthesis. What is the secret of this astonishing success? Perhaps the great versatility in scope and applicability continues to justify its crucial role in the synthesis of more and more complex molecules. However, it has taken more than a century for asymmetric catalytic versions of this reaction to be developed and subsequently extended to a range of aromatic compounds and alkylating agents. Herein we review recent developments in the design and use of catalytic and stereoselective strategies for the alkylation of aromatic systems and synthesis of a wide range of polyfunctionalized enantiomerically enriched compounds.
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Citations
Cited by
Kobayashi, S., Mori, Y., Fossey, J. S., & Salter, M. M. (2011) · Chemical Reviews · doi:10.1021/cr100204f · Cited by 988
Rueping, M., & Nachtsheim, B. J. (2010) · Beilstein Journal of Organic Chemistry · doi:10.3762/bjoc.6.6 · Cited by 667
Organocatalyzed Asymmetric Friedel–Crafts Reactions
Terrasson, V., Marcia de Figueiredo, R., & Campagne, J. M. (2010) · European Journal of Organic Chemistry · doi:10.1002/ejoc.200901492 · Cited by 286
Wang, X., Liu, J., Xu, L., Hao, Z., Wang, L., & Xiao, J. (2015) · RSC Advances · doi:10.1039/c5ra21919a · Cited by 28
Metadata
- Authors
- Bandini, M., Melloni, A., & Umani‐Ronchi, A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2004-01-21
- Volume
- 43
- Issue
- 5
- Pages
- 550-556
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2084852025
- Cited by
- 702
- References
- 0
- FWCI
- 18.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bandini, M., Melloni, A., & Umani‐Ronchi, A. (2004). New Catalytic Approaches in the Stereoselective Friedel–Crafts Alkylation Reaction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200301679
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