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Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology

Open access
Chae, Hee K., Kim, Jaheon, Friedrichs, Olaf Delgado, O’Keeffe, Michael, Yaghi, Omar M.·2003·Angewandte Chemie International Edition

Abstract

Building blocks, octahedral (basic zinc acetate units) and triangular (tritopic carboxylic acid), are assembled into a metal-organic framework (MOF-150) having the topology of the FeS2 pyrite net (see picture). Two independent nets interpenetrate, forming the first example of a fully catenated structure with mixed coordination, an occurrence that is ascribed to the self-dual property of the pyrite net (TCA=4,4′,4′′-Tricarboxytriphenylamine).

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Metadata

Authors
Chae, H. K., Kim, J., Friedrichs, O. D., O’Keeffe, M., & Yaghi, O. M.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2003-08-22
Volume
42
Issue
33
Pages
3907-3909
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2108000066
Cited by
205
References
0
FWCI
6.21
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology. https://app.cochat.ai/papers/10.1002/anie.200351546
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Chae, H. K., Kim, J., Friedrichs, O. D., O’Keeffe, M., & Yaghi, O. M. (2003). Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200351546

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