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Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology
Open accessAbstract
Building blocks, octahedral (basic zinc acetate units) and triangular (tritopic carboxylic acid), are assembled into a metal-organic framework (MOF-150) having the topology of the FeS2 pyrite net (see picture). Two independent nets interpenetrate, forming the first example of a fully catenated structure with mixed coordination, an occurrence that is ascribed to the self-dual property of the pyrite net (TCA=4,4′,4′′-Tricarboxytriphenylamine).
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Cited by
Photoactive Chiral Metal–Organic Frameworks for Light-Driven Asymmetric α-Alkylation of Aldehydes
Wu, P., He, C., Wang, J., Peng, X., Li, X., An, Y., & Duan, C. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305367j · Cited by 445
Fang, Q.-R., Yuan, D.-Q., Sculley, J., Li, J.-R., Han, Z.-B., & Zhou, H.-C. (2010) · Inorganic Chemistry · doi:10.1021/ic101935f · Cited by 309
Construction and Characterization of Structure Models of Crystalline Porous Polymers
Martin, R. L., & Haranczyk, M. (2014) · Crystal Growth & Design · doi:10.1021/cg500158c · Cited by 116
Metadata
- Authors
- Chae, H. K., Kim, J., Friedrichs, O. D., O’Keeffe, M., & Yaghi, O. M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2003-08-22
- Volume
- 42
- Issue
- 33
- Pages
- 3907-3909
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2108000066
- Cited by
- 205
- References
- 0
- FWCI
- 6.21
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology. https://app.cochat.ai/papers/10.1002/anie.200351546
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- Chae, H. K., Kim, J., Friedrichs, O. D., O’Keeffe, M., & Yaghi, O. M. (2003). Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200351546
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