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Aminolysis Route to Monodisperse Titania Nanorods with Tunable Aspect Ratio
Abstract
High-temperature nonhydrolytic aminolysis has been developed as an approach to monodisperse titania nanocrystals by exploiting the chemical modification of reactive titanium isopropoxide with oleic acid as the chelating ligand. Its capabilities for the anisotropic growth of highly crystalline anatase titania nanocrystals (see picture) with controlled size and shape have been demonstrated.
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“Amide elimination facilitates the controlled growth of nanostructures like titania nanorods through the reaction of metal oleates with amines [48] ((4) in Scheme 1).”
From Recent Advances in Metal-Oxide-Based Photoresists for EUV Lithography (2024) · cites this paper as [48]
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Metadata
- Authors
- Zhang, Z., Zhong, X., Liu, S., Li, D., & Han, M.
- Affiliations
- National University of Singapore (SG)
- Institute of Materials Research and Engineering (SG)
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2005-05-24
- Volume
- 44
- Issue
- 22
- Pages
- 3466-3470
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2104697120
- Cited by
- 236
- References
- 38
- Citations by year
- 2026: 2 · 2025: 1 · 2024: 6 · 2023: 4 · 2022: 8 · 2021: 6 · 2020: 8 · 2019: 8 · 2018: 5 · 2017: 14 · 2016: 9 · 2015: 10 · 2014: 17 · 2013: 19 · 2012: 20
- FWCI
- 10.49
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- National University of Singapore (submittedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Physical Sciences › Materials Science › Materials Chemistry › Chemical and Physical Properties of Materials
- Keywords
- titania nanorods, aminolysis, titanium isopropoxide, oleic acid, chelating ligands, anatase, monodisperse nanocrystals, aspect ratio control, anisotropic growth, crystallinity
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