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Exceptional Negative Thermal Expansion in Isoreticular Metal–Organic Frameworks
Open accessAbstract
Shrink when heated: A new model for flexible frameworks is used to simulate the structures and adsorption properties of isoreticular metal–organic frameworks (IRMOFs), such as IRMOF-1 (see picture; Zn silver, C cyan, H white, O red). The structural simulations suggest that the IRMOFs have negative thermalexpansion coefficients over their full temperature ranges of stability.
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Cited by
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Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Self-citationHan, S. S., Mendoza-Cortés, J. L., & Goddard III, W. A. (2009) · Chemical Society Reviews · doi:10.1039/b802430h · Cited by 594
Coudert, F.-X. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00046 · Cited by 528
Adsorption of CO2, CH4, and N2 on Zeolitic Imidazolate Frameworks: Experiments and Simulations
Pérez‐Pellitero, J., Amrouche, H., Siperstein, F. R., Pirngruber, G., Nieto‐Draghi, C., Chaplais, G., Simon‐Masseron, A., Bazer‐Bachi, D., Peralta, D., & Bats, N. (2010) · Chemistry – A European Journal · doi:10.1002/chem.200902144 · Cited by 417
Metadata
- Authors
- Dubbeldam, D., Walton, K. S., Ellis, D. E., & Snurr, R. Q.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2007-05-31
- Volume
- 46
- Issue
- 24
- Pages
- 4496-4499
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2104962402
- Cited by
- 331
- References
- 0
- FWCI
- 16.13
- Type
- journal article
- Language
- en
- Open access
- bronze
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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