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Gas Adsorption Sites in a Large-Pore Metal-Organic Framework
Open accessAbstract
The primary adsorption sites for Ar and N 2 within metal-organic framework-5, a cubic structure composed of Zn 4 O(CO 2 ) 6 units and phenylene links defining large pores 12 and 15 angstroms in diameter, have been identified by single-crystal x-ray diffraction. Refinement of data collected between 293 and 30 kelvin revealed a total of eight symmetry-independent adsorption sites. Five of these are sites on the zinc oxide unit and the organic link; the remaining three sites form a second layer in the pores. The structural integrity and high symmetry of the framework are retained throughout, with negligible changes resulting from gas adsorption.
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Cited by
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A Universal Machine Learning Algorithm for Large-Scale Screening of Materials
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Metadata
- Authors
- Rowsell, J. L. C., Spencer, E. C., Eckert, J., Howard, J. A. K., & Yaghi, O. M.
- Venue
- Science
- Published
- 2005-08-26
- Volume
- 309
- Issue
- 5739
- Pages
- 1350-1354
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1973687047
- Cited by
- 895
- References
- 0
- FWCI
- 31.51
- Type
- journal article
- Language
- en
- Open access
- green
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- Rowsell, J. L. C., Spencer, E. C., Eckert, J., Howard, J. A. K., & Yaghi, O. M. (2005). Gas Adsorption Sites in a Large-Pore Metal-Organic Framework. Science. https://doi.org/10.1126/science.1113247
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