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The “Complex‐in‐a‐Complex” Cations [(acac)2M⊂Ru6(p‐i PrC6H4Me)6(tpt)2(dhbq)3]6+: A Trojan Horse for Cancer Cells
Open accessAbstract
The start of an odyssey? The cytotoxicities of the large cationic arene–ruthenium prismatic cage 16+, and its “complex-in-a-complex” derivatives [(acac)2M⊂1]6+ (M=Pd, Pt; acac=acetylacetonate; see picture), are evaluated in comparison with free [M(acac)2]. The differences in cytotoxicity suggest that, like a “Trojan Horse”, leaching of the guest from the cage once inside a cell accelerates and increases the cytotoxic effect.
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Citations
Cites
Cellular processing of platinum anticancer drugs
Wang, D., & Lippard, S. J. (2005) · Nature Reviews Drug Discovery · doi:10.1038/nrd1691 · Cited by 3,801
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Zeng, L., Gupta, P., Chen, Y., Wang, E., Ji, L., Chao, H., & Chen, Z.-S. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00195a · Cited by 1,017
Zhou, J., Yu, G., & Huang, F. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00898d · Cited by 677
Recent developments in ruthenium anticancer drugs
Levina, A., Mitra, A., & Lay, P. A. (2009) · Metallomics · doi:10.1039/b904071d · Cited by 592
Supramolecular cancer nanotheranostics
Zhou, J., Rao, L., Yu, G., Cook, T. R., Chen, X., & Huang, F. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00011f · Cited by 411
Metadata
- Authors
- Therrien, B., Süss‐Fink, G., Govindaswamy, P., Renfrew, A. K., & Dyson, P. J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-04-28
- Volume
- 47
- Issue
- 20
- Pages
- 3773-3776
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2144114672
- Cited by
- 446
- References
- 1
- FWCI
- 17.50
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: The “Complex‐in‐a‐Complex” Cations [(acac)2M⊂Ru6(p‐i PrC6H4Me)6(tpt)2(dhbq)3]6+: A Trojan Horse for Cancer Cells. https://app.cochat.ai/papers/10.1002/anie.200800186
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- Therrien, B., Süss‐Fink, G., Govindaswamy, P., Renfrew, A. K., & Dyson, P. J. (2008). The “Complex‐in‐a‐Complex” Cations [(acac)2M⊂Ru6(p‐i PrC6H4Me)6(tpt)2(dhbq)3]6+: A Trojan Horse for Cancer Cells. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200800186
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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