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Asymmetric Counteranion‐Directed Transition‐Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes

Liao, Saihu, List, Benjamin·2010·Angewandte Chemie International Edition
DOI 10.1002/anie.200905332
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Abstract

Paired up: A highly active and enantioselective ion-pair epoxidation catalyst, consisting of an achiral MnIII–salen complex and a chiral phosphate counteranion, mediates the epoxidization of a wide range of alkenes with high yields and enantioselectivities (see scheme). The unique role of the counteranion is to stabilize an enantiomorphic conformation of the cationic Mn catalyst.

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Metadata

Authors
Liao, S., & List, B.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2010-01-07
Volume
49
Issue
3
Pages
628-631
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
DOI
10.1002/anie.200905332
OpenAlex
W2129549782
Cited by
210
References
0
FWCI
11.97
Type
journal article
Language
en
Open access
closed
Licence
onlinelibrary.wiley.com/termsAndConditions#vor (vor)

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CoChat. (2026). Citation check: Asymmetric Counteranion‐Directed Transition‐Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes. https://app.cochat.ai/papers/10.1002/anie.200905332
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Liao, S., & List, B. (2010). Asymmetric Counteranion‐Directed Transition‐Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200905332

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