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The Measure of All Rings—N‐Heterocyclic Carbenes
Abstract
Quantification and variation of characteristic properties of different ligand classes is an exciting and rewarding research field. N‐Heterocyclic carbenes (NHCs) are of special interest since their electron richness and structure provide a unique class of ligands and organocatalysts. Consequently, they have found widespread application as ligands in transition‐metal catalysis and organometallic chemistry, and as organocatalysts in their own right. Herein we provide an overview on physicochemical data (electronics, sterics, bond strength) of NHCs that are essential for the design, application, and mechanistic understanding of NHCs in catalysis.
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Cites
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824
Cited by
Computational Ligand Descriptors for Catalyst Design
Durand, D. J., & Fey, N. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00588 · Cited by 406
Organocatalysis in biorefining for biomass conversion and upgrading
Liu, D. (. J. )., & Chen, E. Y.-X. (2014) · Green Chem. · doi:10.1039/c3gc41934g · Cited by 101
Naumann, S., Thomas, A. W., & Dove, A. P. (2016) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00873 · Cited by 97
Metadata
- Authors
- Dröge, T., & Glorius, F.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2010-08-16
- Volume
- 49
- Issue
- 39
- Pages
- 6940-6952
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2109254975
- Cited by
- 1,240
- References
- 1
- FWCI
- 56.04
- Type
- journal article
- Language
- en
- Open access
- closed
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