The DOI matches its Crossref record.
Carboxylation of NH/CH Bonds Using N‐Heterocyclic Carbene Copper(I) Complexes
Abstract
Greenhouse gas makes good: A simple copper-mediated protocol has been developed where NH or CH bonds can be directly functionalized using an easily prepared catalyst. The novel [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I) hydroxide, [Cu(IPr)(OH)], permits the facile activation and carboxylation of NH and CH bonds with pKa values of less than 27.7 (see scheme).
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Citations
Cited by
Ostapowicz, T. G., Schmitz, M., Krystof, M., Klankermayer, J., & Leitner, W. (2013) · Angewandte Chemie · doi:10.1002/ange.201304529 · Cited by 63
Catalytic conversion of carbon dioxide to carboxylic acid derivatives
Liu, A., Yu, B., & He, L. (2015) · Greenhouse Gases Science and Technology · doi:10.1002/ghg.1461 · Cited by 57
Metadata
- Authors
- Boogaerts, I. I. F., Fortman, G. C., Furst, M. R. L., Cazin, C. S. J., & Nolan, S. P.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2010-09-30
- Volume
- 49
- Issue
- 46
- Pages
- 8674-8677
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2151114296
- Cited by
- 348
- References
- 0
- FWCI
- 20.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Boogaerts, I. I. F., Fortman, G. C., Furst, M. R. L., Cazin, C. S. J., & Nolan, S. P. (2010). Carboxylation of NH/CH Bonds Using N‐Heterocyclic Carbene Copper(I) Complexes. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201004153
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