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On the True Photoreactivity Order of {001}, {010}, and {101} Facets of Anatase TiO2 Crystals
Abstract
Contrary to conventional understanding, clean anatase {001} facets exhibit lower photoreactivity than {101} facets. Furthermore, the {010} facets showed the highest photocatalytic reactivity in generating OH radicals and hydrogen evolution. This behavior was revealed by studies on crystals grown hydrothermally to have a predominance of {001}, {101}, or {010} facets (left to right in picture (a) and (b)–(d), respectively).
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Self-citationShape control of CdSe nanocrystals
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Kubacka, A., Fernández-García, M., & Colón, G. (2012) · Chemical Reviews · doi:10.1021/cr100454n · Cited by 2,373
Why is anatase a better photocatalyst than rutile? - Model studies on epitaxial TiO2 films
Luttrell, T., Halpegamage, S., Tao, J., Kramer, A., Sutter, E., & Batzill, M. (2014) · Scientific Reports · doi:10.1038/srep04043 · Cited by 1,544
Recent Advances in Heterogeneous Photocatalytic CO 2 Conversion to Solar Fuels
Li, K., Peng, B., & Peng, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02089 · Cited by 1,355
Titanium Dioxide Crystals with Tailored Facets
Liu, G., Yang, H. G., Pan, J., Yang, Y. Q., Lu, G. Q. (., & Cheng, H.-M. (2014) · Chemical Reviews · doi:10.1021/cr400621z · Cited by 1,084
Self-citationPhotocatalysts with internal electric fields
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Metadata
- Authors
- Pan, J., Liu, G., Lu, G. Q. (., & Cheng, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2011-01-26
- Volume
- 50
- Issue
- 9
- Pages
- 2133-2137
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2140134018
- Cited by
- 1,244
- References
- 6
- FWCI
- 42.03
- Type
- journal article
- Language
- en
- Open access
- closed
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