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Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity
Open accessAbstract
Liquid hydrocarbon fuels play an essential part in the global energy chain, owing to their high energy density and easy transportability. Olefins play a similar role in the production of consumer goods. In a post‐oil society, fuel and olefin production will rely on alternative carbon sources, such as biomass, coal, natural gas, and CO 2. The methanol‐to‐hydrocarbons (MTH) process is a key step in such routes, and can be tuned into production of gasoline‐rich (methanol to gasoline; MTG) or olefin‐rich (methanol to olefins; MTO) product mixtures by proper choice of catalyst and reaction conditions. This Review presents several commercial MTH projects that have recently been realized, and also fundamental research into the synthesis of microporous materials for the targeted variation of selectivity and lifetime of the catalysts.
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Cited by
Direct conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst
Gao, P., Li, S., Bu, X., Dang, S., Liu, Z., Wang, H., Zhong, L., Qiu, M., Yang, C., Cai, J., et al. (2017) · Nature Chemistry · doi:10.1038/nchem.2794 · Cited by 1,122
Grundner, S., Markovits, M. A. C., Li, G., Tromp, M., Pidko, E. A., Hensen, E. J. M., Jentys, A., Sanchez-Sanchez, M., & Lercher, J. A. (2015) · Nature Communications · doi:10.1038/ncomms8546 · Cited by 773
Cheng, K., Zhou, W., Kang, J., He, S., Shi, S., Zhang, Q., Pan, Y., Wen, W., & Wang, Y. (2017) · Chem · doi:10.1016/j.chempr.2017.05.007 · Cited by 533
Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis
Gao, P., Dang, S., Li, S., Bu, X., Liu, Z., Qiu, M., Yang, C., Wang, H., Zhong, L., Han, Y., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b02649 · Cited by 533
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Metadata
- Authors
- Olsbye, U., Svelle, S., Bjørgen, M., Beato, P., Janssens, T. V. W., Joensen, F., Bordiga, S., & Lillerud, K. P.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-04-18
- Volume
- 51
- Issue
- 24
- Pages
- 5810-5831
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2053428471
- Cited by
- 1,802
- References
- 0
- FWCI
- 49.82
- Type
- journal article
- Language
- en
- Open access
- green
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- Olsbye, U., Svelle, S., Bjørgen, M., Beato, P., Janssens, T. V. W., Joensen, F., Bordiga, S., & Lillerud, K. P. (2012). Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201103657
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