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Actuation of Asymmetric Cyclopropanation Catalysts: Reversible Single‐Crystal to Single‐Crystal Reduction of Metal–Organic Frameworks

Falkowski, Joseph M., Wang, Cheng, Liu, Sophie, Lin, Wenbin·2011·Angewandte Chemie International Edition

Abstract

To and fro: Chiral metal–organic frameworks (CMOFs) derived from redox-active ruthenium/salen building blocks exhibited reversible single-crystal to single-crystal reduction and reoxidation. The catalytically inactive RuIII CMOFs (green; see picture) were reduced to RuII CMOFs (red) that were highly active for the asymmetric cyclopropanation of alkenes with very high diastereo- and enantioselectivities.

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Metadata

Authors
Falkowski, J. M., Wang, C., Liu, S., & Lin, W.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2011-08-08
Volume
50
Issue
37
Pages
8674-8678
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2130400057
Cited by
177
References
1
FWCI
14.08
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Actuation of Asymmetric Cyclopropanation Catalysts: Reversible Single‐Crystal to Single‐Crystal Reduction of Metal–Organic Frameworks. https://app.cochat.ai/papers/10.1002/anie.201104086
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Falkowski, J. M., Wang, C., Liu, S., & Lin, W. (2011). Actuation of Asymmetric Cyclopropanation Catalysts: Reversible Single‐Crystal to Single‐Crystal Reduction of Metal–Organic Frameworks. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201104086

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