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Importance of the Metal–Oxide Interface in Catalysis: In Situ Studies of the Water–Gas Shift Reaction by Ambient‐Pressure X‐ray Photoelectron Spectroscopy
Abstract
Where oxide and metals meet: The activation of an efficient associative mechanistic pathway for the water–gas shift reaction by an oxide–metal interface leads to an increase in the catalytic activity of nanoparticles of ceria deposited on Cu(111) or Au(111) by more than an order of magnitude (see graph). In situ experiments demonstrated that a carboxy species formed at the metal–oxide interface is the critical intermediate in the reaction.
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Mhadeshwar, A. B., & Vlachos, D. G. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp048698g · Cited by 159
Cited by
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Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2
Graciani, J., Mudiyanselage, K., Xu, F., Baber, A. E., Evans, J., Senanayake, S. D., Stacchiola, D. J., Liu, P., Hrbek, J., Sanz, J. F., et al. (2014) · Science · doi:10.1126/science.1253057 · Cited by 1,452
Self-citationCeria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis?
Trovarelli, A., & Llorca, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01246 · Cited by 781
Synergetic interaction between neighbouring platinum monomers in CO2 hydrogenation
Li, H., Wang, L., Dai, Y., Pu, Z., Lao, Z., Chen, Y., Wang, M., Zheng, X., Zhu, J., Zhang, W., et al. (2018) · Nature Nanotechnology · doi:10.1038/s41565-018-0089-z · Cited by 770
Dinh, C.-T., Jain, A., de Arquer, F. P. G., De Luna, P., Li, J., Wang, N., Zheng, X., Cai, J., Gregory, B. Z., Voznyy, O., et al. (2018) · Nature Energy · doi:10.1038/s41560-018-0296-8 · Cited by 717
Metadata
- Authors
- Mudiyanselage, K., Senanayake, S. D., Feria, L., Kundu, S., Baber, A. E., Graciani, J., Vidal, A. B., Agnoli, S., Evans, J., Chang, R., Axnanda, S., Liu, Z., Sanz, J. F., Liu, P., Rodriguez, J. A., & Stacchiola, D. J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-04-09
- Volume
- 52
- Issue
- 19
- Pages
- 5101-5105
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2148587445
- Cited by
- 321
- References
- 1
- FWCI
- 15.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mudiyanselage, K., Senanayake, S. D., Feria, L., Kundu, S., Baber, A. E., Graciani, J., Vidal, A. B., Agnoli, S., Evans, J., Chang, R., Axnanda, S., Liu, Z., Sanz, J. F., Liu, P., Rodriguez, J. A., & Stacchiola, D. J. (2013). Importance of the Metal–Oxide Interface in Catalysis: In Situ Studies of the Water–Gas Shift Reaction by Ambient‐Pressure X‐ray Photoelectron Spectroscopy. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201210077
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