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Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2
Abstract
Converting CO 2 into methanol by catalysis: By hydrogenating CO 2 , scientists can transform a greenhouse gas into methanol, a desirable fuel. Graciani et al. cast copper in the role of the highly active catalyst for this reaction by putting copper particles on cerium oxide. The interface between the cerium oxide and the copper enables the reverse water-gas shift reaction that converts CO 2 into CO, which reacts more readily with hydrogen to make methanol. This result takes a step forward in innovating catalysts for this environmentally friendly process. Science , this issue p. 546
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Cites
From ultrasoft pseudopotentials to the projector augmented-wave method
Kresse, G., & Joubert, D. (1999) · Physical Review B · doi:10.1103/physrevb.59.1758 · Cited by 85,307
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Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface
Kattel, S., Liu, P., & Chen, J. G. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05362 · Cited by 1,259
Self-citationDirect conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst
Gao, P., Li, S., Bu, X., Dang, S., Liu, Z., Wang, H., Zhong, L., Qiu, M., Yang, C., Cai, J., et al. (2017) · Nature Chemistry · doi:10.1038/nchem.2794 · Cited by 1,122
Zhang, L., Zhao, Z., & Gong, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201612214 · Cited by 1,048
Klankermayer, J., Wesselbaum, S., Beydoun, K., & Leitner, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507458 · Cited by 856
Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis
Gao, P., Dang, S., Li, S., Bu, X., Liu, Z., Qiu, M., Yang, C., Wang, H., Zhong, L., Han, Y., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b02649 · Cited by 533
Metadata
- Authors
- Graciani, J., Mudiyanselage, K., Xu, F., Baber, A. E., Evans, J., Senanayake, S. D., Stacchiola, D. J., Liu, P., Hrbek, J., Sanz, J. F., & Rodriguez, J. A.
- Venue
- Science
- Published
- 2014-08
- Volume
- 345
- Issue
- 6196
- Pages
- 546-550
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W1991692033
- Cited by
- 1,452
- References
- 1
- FWCI
- 34.05
- Type
- journal article
- Language
- en
- Open access
- closed
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- Graciani, J., Mudiyanselage, K., Xu, F., Baber, A. E., Evans, J., Senanayake, S. D., Stacchiola, D. J., Liu, P., Hrbek, J., Sanz, J. F., & Rodriguez, J. A. (2014). Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2. Science. https://doi.org/10.1126/science.1253057
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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