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A Controllable Gate Effect in Cobalt(II) Organic Frameworks by Reversible Structure Transformations
Abstract
With H2 O or NH3 stimuli, the blue cobalt-based metal-organic framework (MOF) BP can reversibly transform to red RP. The removal/recovery of terephthalate ligands accompanied by the transformation leads to a gate effect, which allows the encapsulation and release of small solvent molecules under certain conditions. This is the first example of topology transformation from a self-penetrating to interpenetrating net in 3D MOFs.
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Cited by
Proton-conductive metal-organic frameworks: Recent advances and perspectives
Li, A.-L., Gao, Q., Xu, J., & Bu, X.-H. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.03.027 · Cited by 320
Self-citationLiu, W., Yin, R., Xu, X., Zhang, L., Shi, W., & Cao, X. (2019) · Advanced Science · doi:10.1002/advs.201802373 · Cited by 304
Gating effect for gas adsorption in microporous materials—mechanisms and applications
Chen, K., Mousavi, S. H., Singh, R., Snurr, R. Q., Li, G., & Webley, P. A. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00822f · Cited by 133
Jia, Y.-Y., Liu, X.-T., Feng, R., Zhang, S.-Y., Zhang, P., He, Y.-B., Zhang, Y.-H., & Bu, X.-H. (2017) · Crystal Growth & Design · doi:10.1021/acs.cgd.7b00119 · Cited by 18
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Metadata
- Authors
- Chen, Q., Chang, Z., Song, W., Song, H., Song, H., Hu, T., & Bu, X.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-09-13
- Volume
- 52
- Issue
- 44
- Pages
- 11550-11553
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2106535633
- Cited by
- 319
- References
- 0
- FWCI
- 21.53
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, Q., Chang, Z., Song, W., Song, H., Song, H., Hu, T., & Bu, X. (2013). A Controllable Gate Effect in Cobalt(II) Organic Frameworks by Reversible Structure Transformations. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201306304
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