The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.
Simple and Compelling Biomimetic Metal–Organic Framework Catalyst for the Degradation of Nerve Agent Simulants
Abstract
Inspired by biology, in which a bimetallic hydroxide‐bridged zinc(II)‐containing enzyme is utilized to catalytically hydrolyze phosphate ester bonds, the utility of a zirconium(IV)‐cluster‐containing metal–organic framework as a catalyst for the methanolysis and hydrolysis of phosphate‐based nerve agent simulants was examined. The combination of the strong Lewis‐acidic Zr IV and bridging hydroxide anions led to ultrafast half‐lives for these solvolysis reactions. This is especially remarkable considering that the actual catalyst loading was a mere 0.045 % as a result of the surface‐only catalysis observed.
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Cites
Metal-organic framework materials as catalysts
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Self-citationA New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
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Synthesis and Stability of Tagged UiO-66 Zr-MOFs
Kandiah, M., Nilsen, M. H., Usseglio, S., Jakobsen, S., Olsbye, U., Tilset, M., Larabi, C., Quadrelli, E. A., Bonino, F., & Lillerud, K. P. (2010) · Chemistry of Materials · doi:10.1021/cm102601v · Cited by 2,031
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Self-citationModulated Synthesis of Zr‐Based Metal–Organic Frameworks: From Nano to Single Crystals
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Nanomaterials with enzyme-like characteristics (nanozymes): next-generation artificial enzymes
Wei, H., & Wang, E. (2013) · Chemical Society Reviews · doi:10.1039/c3cs35486e · Cited by 3,779
Zr-based metal–organic frameworks: design, synthesis, structure, and applications
Bai, Y., Dou, Y., Xie, L.-H., Rutledge, W., Li, J.-R., & Zhou, H.-C. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00837a · Cited by 2,545
Bavykina, A., Kolobov, N., Khan, I. S., Bau, J. A., Ramirez, A., & Gascon, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00685 · Cited by 1,754
Metal–organic and covalent organic frameworks as single-site catalysts
Rogge, S. M. J., Bavykina, A., Hajek, J., Garcia, H., Olivos-Suarez, A. I., Sepúlveda-Escribano, A., Vimont, A., Clet, G., Bazin, P., Kapteijn, F., et al. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00033b · Cited by 1,077
Metal–Organic Frameworks against Toxic Chemicals
Islamoglu, T., Chen, Z., Wasson, M. C., Buru, C. T., Kirlikovali, K. O., Afrin, U., Mian, M. R., & Farha, O. K. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00828 · Cited by 707
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Metadata
- Authors
- Katz, M. J., Mondloch, J. E., Totten, R. K., Park, J. K., Nguyen, S. T., Farha, O. K., & Hupp, J. T.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-11-24
- Volume
- 53
- Issue
- 2
- Pages
- 497-501
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2022582494
- Cited by
- 443
- References
- 26
- FWCI
- 13.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- Katz, M. J., Mondloch, J. E., Totten, R. K., Park, J. K., Nguyen, S. T., Farha, O. K., & Hupp, J. T. (2014). Simple and Compelling Biomimetic Metal–Organic Framework Catalyst for the Degradation of Nerve Agent Simulants. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201307520
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