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Cited by 367

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“Metal‐Free” Catalytic Oxygen Reduction Reaction on Heteroatom‐Doped Graphene is Caused by Trace Metal Impurities

Wang, Lu, Ambrosi, Adriano, Pumera, Martin·2013·Angewandte Chemie International Edition

Abstract

The oxygen reduction reaction (ORR) is of high industrial importance. There is a large body of literature showing that metal‐based catalytic nanoparticles (e.g. Co, Mn, Fe or hybrid Mn/Co‐based nanoparticles) supported on graphene act as efficient catalysts for the ORR. A significant research effort is also directed to the so‐called “metal‐free” oxygen reduction reaction on heteroatom‐doped graphene surfaces. While such studies of the ORR on nonmetallic heteroatom‐doped graphene are advertised as “metal‐free” there is typically no sufficient effort to characterize the doped materials to verify that they are indeed free of any trace metal. Here we argue that the claimed “metal‐free” electrocatalysis of the oxygen reduction reaction on heteroatom‐doped graphene is caused by metallic impurities present within the graphene materials.

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Metadata

Authors
Wang, L., Ambrosi, A., & Pumera, M.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2013-11-25
Volume
52
Issue
51
Pages
13818-13821
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2082053544
Cited by
367
References
1
FWCI
16.59
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: “Metal‐Free” Catalytic Oxygen Reduction Reaction on Heteroatom‐Doped Graphene is Caused by Trace Metal Impurities. https://app.cochat.ai/papers/10.1002/anie.201309171
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Wang, L., Ambrosi, A., & Pumera, M. (2013). “Metal‐Free” Catalytic Oxygen Reduction Reaction on Heteroatom‐Doped Graphene is Caused by Trace Metal Impurities. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201309171

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