Cited by 1,240Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsHydrogen Storage and Materials

The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.

Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles

Popczun, Eric J., Read, Carlos G., Roske, Christopher W., Lewis, Nathan S., Schaak, Raymond E.·2014·Angewandte Chemie International Edition

DOI 10.1002/anie.201402646

Open this paper in CoChat — free account

Abstract

Nanoparticles of cobalt phosphide, CoP, have been prepared and evaluated as electrocatalysts for the hydrogen evolution reaction (HER) under strongly acidic conditions (0.50 M H2SO4, pH 0.3). Uniform, multi-faceted CoP nanoparticles were synthesized by reacting Co nanoparticles with trioctylphosphine. Electrodes comprised of CoP nanoparticles on a Ti support (2 mg cm(-2) mass loading) produced a cathodic current density of 20 mA cm(-2) at an overpotential of -85 mV. The CoP/Ti electrodes were stable over 24 h of sustained hydrogen production in 0.50 M H2SO4. The activity was essentially unchanged after 400 cyclic voltammetric sweeps, suggesting long-term viability under operating conditions. CoP is therefore amongst the most active, acid-stable, earth-abundant HER electrocatalysts reported to date.

Integrity signals

Registry

Crossref · 10.1002/anie.201402646

Cites

31 of 31 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Solar Water Splitting Cells
Walter, M. G., Warren, E. L., McKone, J. R., Boettcher, S. W., Mi, Q., Santori, E. A., & Lewis, N. S. (2010) · Chemical Reviews · doi:10.1021/cr1002326 · Cited by 9,388
Self-citation
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Self-citation
The Artificial Leaf
Nocera, D. G. (2012) · Accounts of Chemical Research · doi:10.1021/ar2003013 · Cited by 1,704
Molybdenum Boride and Carbide Catalyze Hydrogen Evolution in both Acidic and Basic Solutions
Vrubel, H., & Hu, X. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201207111 · Cited by 1,313
Hydrogen‐Evolution Catalysts Based on Non‐Noble Metal Nickel–Molybdenum Nitride Nanosheets
Chen, W., Sasaki, K., Ma, C., Frenkel, A. I., Marinković, N., Muckerman, J. T., Zhu, Y., & Adžić, R. R. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201200699 · Cited by 1,306
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
Kong, D., Cha, J. J., Wang, H., Lee, H. R., & Cui, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42413h · Cited by 1,031
Mixed Close-Packed Cobalt Molybdenum Nitrides as Non-noble Metal Electrocatalysts for the Hydrogen Evolution Reaction
Cao, B., Veith, G. M., Neuefeind, J. C., Adzic, R. R., & Khalifah, P. G. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4081056 · Cited by 998

Flagged first, then by citations

Show all 31 references

Sorted by citations

Items 301–400 of 1,000

Free-standing nanoporous NiMnFeMo alloy: An efficient non-precious metal electrocatalyst for water splitting
Liu, H., Xi, C., Xin, J., Zhang, G., Zhang, S., Zhang, Z., Huang, Q., Li, J., Liu, H., & Kang, J. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.126530 · Cited by 147
Carbon-coated hollow mesoporous FeP microcubes: an efficient and stable electrocatalyst for hydrogen evolution
Zhu, X., Liu, M., Liu, Y., Chen, R., Nie, Z., Li, J., & Yao, S. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta01923d · Cited by 144
One-Step Synthesis of a Self-Supported Copper Phosphide Nanobush for Overall Water Splitting
Wei, S., Qi, K., Jin, Z., Cao, J., Zheng, W., Chen, H., & Cui, X. (2016) · ACS Omega · doi:10.1021/acsomega.6b00366 · Cited by 146
Mechanistic insight into oxygen evolution electrocatalysis of surface phosphate modified cobalt phosphide nanorod bundles and their superior performance for overall water splitting
Ai, L., Niu, Z., & Jiang, J. (2017) · Electrochimica Acta · doi:10.1016/j.electacta.2017.05.032 · Cited by 144
Synthesis and X-ray Characterization of Cobalt Phosphide (Co 2 P) Nanorods for the Oxygen Reduction Reaction
Doan‐Nguyen, V. V. T., Zhang, S., Trigg, E. B., Agarwal, R., Li, J., Su, D., Winey, K. I., & Murray, C. B. (2015) · ACS Nano · doi:10.1021/acsnano.5b02191 · Cited by 144
Ultrasmall Cu7S4@MoS2 Hetero‐Nanoframes with Abundant Active Edge Sites for Ultrahigh‐Performance Hydrogen Evolution
Xu, J. J., Cui, J., Guo, C., Zhao, Z., Jiang, R., Xu, S., Zhuang, Z., Huang, Y., Wang, L., & Li, Y. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201600686 · Cited by 143
A review of the electrocatalysts on hydrogen evolution reaction with an emphasis on Fe, Co and Ni-based phosphides
Ge, Z., Fu, B., Zhao, J., Li, X., Ma, B., & Chen, Y. (2020) · Journal of Materials Science · doi:10.1007/s10853-020-05010-w · Cited by 145
Extraordinarily Durable Graphdiyne-Supported Electrocatalyst with High Activity for Hydrogen Production at All Values of pH
Xue, Y., Li, J., Xue, Z., Li, Y., Li, D., Li, D., Yang, W., & Li, Y. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b12655 · Cited by 142
Atom Doping Engineering of Transition Metal Phosphides for Hydrogen Evolution Reactions
Bai, H., Chen, D., Ma, Q., Qin, R., Xu, H., Zhao, Y., Chen, J., & Mu, S. C. (2022) · Electrochemical Energy Reviews · doi:10.1007/s41918-022-00161-7 · Cited by 144
Amorphous Phosphorus-Incorporated Cobalt Molybdenum Sulfide on Carbon Cloth: An Efficient and Stable Electrocatalyst for Enhanced Overall Water Splitting over Entire pH Values
Ray, C., Lee, S. C., Sankar, K. V., Jin, B., Lee, J., Park, J. H., & Jun, S. C. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b11192 · Cited by 142
Vanadium carbide nanoparticles encapsulated in graphitic carbon network nanosheets: A high-efficiency electrocatalyst for hydrogen evolution reaction
Peng, X. F., Hu, L., Wang, L., Zhang, X., Fu, J., Huo, K., Lee, L. Y. S., Wong, K., & Chu, P. K.-H. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.06.020 · Cited by 140
Recent advances in transition-metal phosphide electrocatalysts: Synthetic approach, improvement strategies and environmental applications
Li, X., Xing, W., Hu, T., Luo, K., Wang, J., & Tang, W. (2022) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2022.214811 · Cited by 138
N-doped carbon shell coated CoP nanocrystals encapsulated in porous N-doped carbon substrate as efficient electrocatalyst of water splitting
Peng, Z., Yu, Y., Jiang, D., Wu, Y., Xia, B. Y., & Dong, Z. (2018) · Carbon · doi:10.1016/j.carbon.2018.12.085 · Cited by 137
Highly active non-noble electrocatalyst from Co2P/Ni2P nanohybrids for pH-universal hydrogen evolution reaction
Li, D., Liao, L., Zhou, H., Zhao, Y., Cai, F., Zeng, J., Liu, F., Wu, H., Tang, D., & Yu, F. (2020) · Materials Today Physics · doi:10.1016/j.mtphys.2020.100314 · Cited by 137
Cobalt–Cobalt Phosphide Nanoparticles@Nitrogen‐Phosphorus Doped Carbon/Graphene Derived from Cobalt Ions Adsorbed Saccharomycete Yeasts as an Efficient, Stable, and Large‐Current‐Density Electrode for Hydrogen Evolution Reactions
Li, G., Yu, J., Jia, J. F., Yang, L., Zhao, L., Zhou, W., & Liu, H. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201801332 · Cited by 135
Cobalt based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage
Hua, Y. X., Li, X., Chen, C., & Pang, H. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.03.163 · Cited by 137
Size Effects of Platinum Nanoparticles in the Photocatalytic Hydrogen Production Over 3D Mesoporous Networks of CdS and Pt Nanojunctions
Vamvasakis, I., Liu, B., & Armatas, G. S. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201603292 · Cited by 134
Enhancing Oxygen Evolution Reaction at High Current Densities on Amorphous‐Like Ni–Fe–S Ultrathin Nanosheets via Oxygen Incorporation and Electrochemical Tuning
Zhang, J., Hu, Y., Liu, D., Yu, Y., & Zhang, B. (2016) · Advanced Science · doi:10.1002/advs.201600343 · Cited by 133
Iron oxide and phosphide encapsulated within N,P-doped microporous carbon nanofibers as advanced tri-functional electrocatalyst toward oxygen reduction/evolution and hydrogen evolution reactions and zinc-air batteries
Wang, M., Zhang, C., Meng, T., Pu, Z., Jin, H., He, D., Zhang, J., & Mu, S. C. (2018) · Journal of Power Sources · doi:10.1016/j.jpowsour.2018.12.056 · Cited by 133
Density functional theory calculations: A powerful tool to simulate and design high-performance energy storage and conversion materials
Wu, X., Kang, F., Duan, W., & Li, J. Z. (2019) · Progress in Natural Science Materials International · doi:10.1016/j.pnsc.2019.04.003 · Cited by 136
A first-principles examination of conducting monolayer 1T′-MX 2 (M = Mo, W; X = S, Se, Te): promising catalysts for hydrogen evolution reaction and its enhancement by strain
Putungan, D. B., Lin, S., & Kuo, J. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp03799a · Cited by 132
Amorphous molybdenum sulfide quantum dots: an efficient hydrogen evolution electrocatalyst in neutral medium
Dinda, D., Ahmed, M. E., Mandal, S., Mondal, B., & Saha, S. K. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta06101j · Cited by 132
Highly Efficient Hydrogen Evolution from a Mesoporous Hybrid of Nickel Phosphide Nanoparticles Anchored on Cobalt Phosphosulfide/Phosphide Nanosheet Arrays
Sun, J., Ren, M., Yu, L., Yang, Z., Xie, L., Tian, F., Yu, Y., Ren, Z., Chen, S., & Zhou, H. (2019) · Small · doi:10.1002/smll.201804272 · Cited by 132
Rugae-like FeP nanocrystal assembly on a carbon cloth: an exceptionally efficient and stable cathode for hydrogen evolution
Yang, X., Lu, A., Zhu, Y., Min, S., Hedhili, M. N., Han, Y., Huang, K., & Li, L. (2015) · Nanoscale · doi:10.1039/c5nr02375k · Cited by 133
Electrodeposition of nickel–phosphorus nanoparticles film as a Janus electrocatalyst for electro-splitting of water
Liu, Q., Gu, S., & Li, C. M. (2015) · Journal of Power Sources · doi:10.1016/j.jpowsour.2015.09.027 · Cited by 130
Space-Confined Earth-Abundant Bifunctional Electrocatalyst for High-Efficiency Water Splitting
Tang, Y., Fang, X., Zhang, X., Fernandes, G., Yan, Y. S., Yan, D., Xiang, X., & He, J. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b10338 · Cited by 131
Enhanced Pyroelectric Catalysis of BaTiO3 Nanowires for Utilizing Waste Heat in Pollution Treatment
Wu, J., Qin, N., Yuan, B., Lin, E., & Bao, D. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b11158 · Cited by 130
Co-Mo-B Nanoparticles as a non-precious and efficient Bifunctional Electrocatalyst for Hydrogen and Oxygen Evolution
Gupta, S., Patel, N., Fernandes, R., Hanchate, S., Miotello, A., & Kothari, D. C. (2017) · Electrochimica Acta · doi:10.1016/j.electacta.2017.02.100 · Cited by 129
Three-Dimensional Dendritic Structures of NiCoMo as Efficient Electrocatalysts for the Hydrogen Evolution Reaction
Gao, D., Guo, J., Cui, X., Yang, L., Yang, Y., He, H., Xiao, P., & Zhang, Y. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b04009 · Cited by 129
Highly branched cobalt phosphide nanostructures for hydrogen-evolution electrocatalysis
Popczun, E. J., Roske, C. W., Read, C. G., Crompton, J. C., McEnaney, J. M., Callejas, J. F., Lewis, N. S., & Schaak, R. E. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta06642a · Cited by 130
Self-citation
Ternary metal phosphide nanosheets as a highly efficient electrocatalyst for water reduction to hydrogen over a wide pH range from 0 to 14
Han, A., Chen, H., Zhang, H., Sun, Z., & Du, P. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta02297a · Cited by 126
A hierarchically porous nickel–copper phosphide nano-foam for efficient electrochemical splitting of water
Li, W., Goh, K., Birer, Ö., Karahan, H. E., Chang, J., Zhai, S., Chen, X., & Chen, Y. (2017) · Nanoscale · doi:10.1039/c6nr09864a · Cited by 127
Metal–organic framework-derived nickel phosphides as efficient electrocatalysts toward sustainable hydrogen generation from water splitting
Tian, T., Ai, L., & Jiang, J. (2015) · RSC Advances · doi:10.1039/c4ra15680c · Cited by 126
Recent Methods for the Synthesis of Noble-Metal-Free Hydrogen-Evolution Electrocatalysts: From Nanoscale to Sub-nanoscale
Wang, J., Zhang, H., & Wang, X. (2017) · Small Methods · doi:10.1002/smtd.201700118 · Cited by 126
An overview of the active sites in transition metal electrocatalysts and their practical activity for hydrogen evolution reaction
Zhang, X., Xie, J., Ma, Y., Dong, B., Liu, C., & Chai, Y. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.132312 · Cited by 125
Tungsten nitride nanorods array grown on carbon cloth as an efficient hydrogen evolution cathode at all pH values
Shi, J., Pu, Z., Liu, Q., Asiri, A. M., Hu, J., & Sun, X. (2014) · Electrochimica Acta · doi:10.1016/j.electacta.2014.12.096 · Cited by 124
Catalyzing overall water splitting at an ultralow cell voltage of 1.42 V via coupled Co-doped NiO nanosheets with carbon
Yang, H., Chen, Z., Hao, W., Xu, H., Guo, Y., & Wu, R. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.04.021 · Cited by 124
Hierarchically porous nickel–cobalt phosphide nanoneedle arrays loaded micro-carbon spheres as an advanced electrocatalyst for overall water splitting application
Hoa, V. H., Tran, D. T., Le, H. T., Kim, N. H., & Lee, J. H. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.04.017 · Cited by 124
Carbon‐Based Photocathode Materials for Solar Hydrogen Production
Bellani, S., Antognazza, M. R., & Bonaccorso, F. (2018) · Advanced Materials · doi:10.1002/adma.201801446 · Cited by 123
CoP for hydrogen evolution: implications from hydrogen adsorption
Hu, G., Tang, Q. H., & Jiang, D. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp04011j · Cited by 122
Co-axial heterostructures integrating palladium/titanium dioxide with carbon nanotubes for efficient electrocatalytic hydrogen evolution
Valenti, G., Boni, A., Melchionna, M., Cargnello, M., Nasi, L., Bertoni, G., Gorte, R. J., Marcaccio, M., Rapino, S., Bonchio, M., et al. (2016) · Nature Communications · doi:10.1038/ncomms13549 · Cited by 125
A Cu 3 P–CoP hybrid nanowire array: a superior electrocatalyst for acidic hydrogen evolution reactions
Du, H., Zhang, X., Tan, Q., Kong, R., & Qu, F. (2017) · Chemical Communications · doi:10.1039/c7cc07802a · Cited by 121
Two-dimensional dual carbon-coupled defective nickel quantum dots towards highly efficient overall water splitting
Chen, Z., Xu, H., Ha, Y., Li, X., Liu, M., & Wu, R. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.03.032 · Cited by 121
First-row transition metal polypyridine complexes that catalyze proton to hydrogen reduction
Tong, L., Duan, L., Zhou, A., & Thummel, R. P. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213079 · Cited by 123
Mild and Selective Hydrogenation of Nitrate to Ammonia in the Absence of Noble Metals
Wei, L., Liu, D., Rosales, B. A., Evans, J. W., & Vela, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05338 · Cited by 123
Ultrathin MoS2 nanosheets growing within an in-situ-formed template as efficient electrocatalysts for hydrogen evolution
Liu, N., Yang, L., Wang, S., Zhong, Z., He, S., Yang, X., Gao, Q., & Tang, Y. (2015) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.11.039 · Cited by 120
High Performance Electrocatalytic Reaction of Hydrogen and Oxygen on Ruthenium Nanoclusters
Ye, R., Liu, Y., Peng, Z., Wang, T., Jalilov, A. S., Yakobson, B. I., Wei, S., & Tour, J. M. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b15725 · Cited by 120
Recent advances of nonprecious and bifunctional electrocatalysts for overall water splitting
Shang, X., Tang, J., Dong, B., & Sun, Y. (2020) · Sustainable Energy & Fuels · doi:10.1039/d0se00466a · Cited by 120
Three-dimensional amorphous tungsten-doped nickel phosphide microsphere as an efficient electrocatalyst for hydrogen evolution
Jin, Z., Li, P., Huang, X., Zeng, G., Jin, Y., Zheng, B., & Xiao, D. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta04434g · Cited by 119
Facile one-step synthesis of phosphorus-doped CoS2 as efficient electrocatalyst for hydrogen evolution reaction
Zhang, J., Liu, Y., Xia, B., Sun, C., Liu, Y., Liu, P., & Gao, D. (2017) · Electrochimica Acta · doi:10.1016/j.electacta.2017.11.043 · Cited by 118
Strategies on improving the electrocatalytic hydrogen evolution performances of metal phosphides
Yu, W., Gao, Y., Chen, Z., Zhao, Y., Wu, Z., & Wang, L. (2021) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(21)63855-x · Cited by 119
Nickel Diselenide Ultrathin Nanowires Decorated with Amorphous Nickel Oxide Nanoparticles for Enhanced Water Splitting Electrocatalysis
Li, H., Chen, S., Lin, H., Xu, X., Yang, H., Song, L., & Wang, X. (2017) · Small · doi:10.1002/smll.201701487 · Cited by 117
Effective Electrocatalytic Hydrogen Evolution in Neutral Medium Based on 2D MoP/MoS 2 Heterostructure Nanosheets
Wu, A., Gu, Y., Xie, Y. H., Tian, C., Yan, H., Wang, D., Zhang, X., Cai, Z., & Fu, H. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b07415 · Cited by 118
Anion-mediated transition metal electrocatalysts for efficient water electrolysis: Recent advances and future perspectives
Boppella, R., Tan, J., Yun, J., Manorama, S. V., & Moon, J. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213552 · Cited by 119
Ultrafine Molybdenum Carbide Nanoparticles Composited with Carbon as a Highly Active Hydrogen‐Evolution Electrocatalyst
Ma, R., Zhou, Y., Chen, Y., Li, P., Liu, Q., & Wang, J. (2015) · Angewandte Chemie · doi:10.1002/ange.201506727 · Cited by 116
Basics, developments, and strategies of transition metal phosphides toward electrocatalytic water splitting: beyond noble metal catalysts
Lee, Y., Jeong, W., Hwang, Y. J., An, B., Lee, H., Jeong, H., Kim, G., Park, Y., Kim, M.-Y., & Ha, D. (2024) · Journal of Materials Chemistry A · doi:10.1039/d4ta04455j · Cited by 118
Ultrasmall Ru 2 P nanoparticles on graphene: a highly efficient hydrogen evolution reaction electrocatalyst in both acidic and alkaline media
Liu, T., Wang, S., Zhang, Q., Chen, L., Hu, W., & Li, C. M. (2018) · Chemical Communications · doi:10.1039/c8cc01166d · Cited by 116
Robustly photogenerating H2 in water using FeP/CdS catalyst under solar irradiation
Cheng, H., Lv, X., Cao, S., Zhao, Z., Chen, Y., & Fu, W. (2016) · Scientific Reports · doi:10.1038/srep19846 · Cited by 116
Tailoring of cobalt phosphide anchored nitrogen and sulfur co-doped three dimensional graphene hybrid: Boosted electrocatalytic performance towards hydrogen evolution reaction
Karaman, C., Karaman, O., Atar, N., & Yola, M. L. (2021) · Electrochimica Acta · doi:10.1016/j.electacta.2021.138262 · Cited by 115
Molybdenum Phosphosulfide: An Active, Acid‐Stable, Earth‐Abundant Catalyst for the Hydrogen Evolution Reaction
Kibsgaard, J., & Jaramillo, T. F. (2014) · Angewandte Chemie · doi:10.1002/ange.201408222 · Cited by 114
An electron deficiency strategy for enhancing hydrogen evolution on CoP nano-electrocatalysts
Liao, H., Sun, Y., Dai, C., Du, Y., Xi, S., Liu, F., Yu, L., Yang, W., Hou, Y., Fisher, A. C., et al. (2018) · Nano Energy · doi:10.1016/j.nanoen.2018.05.060 · Cited by 113
Hierarchical β‐Mo 2 C Nanotubes Organized by Ultrathin Nanosheets as a Highly Efficient Electrocatalyst for Hydrogen Production
Ma, F., Wu, H. B., Xia, B. Y., Xu, C., & Lou, X. W. (2015) · Angewandte Chemie · doi:10.1002/ange.201508715 · Cited by 113
An overview of heteroatom doped cobalt phosphide for efficient electrochemical water splitting
Wang, Q., He, R., Yang, F., Tian, X., Sui, H., & Feng, L. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.141056 · Cited by 114
MoS2 Nanosheets Supported on 3D Graphene Aerogel as a Highly Efficient Catalyst for Hydrogen Evolution
Zhao, Y., Xie, X., Zhang, J., Liu, H., Ahn, H., Sun, K., & Wang, G. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201501964 · Cited by 112
Self-supported porous Ni-Fe-P composite as an efficient electrocatalyst for hydrogen evolution reaction in both acidic and alkaline medium
Ma, Z., Li, R., Wang, M., Meng, H., Zhang, F., Bao, X., Tang, B. H., & Wang, X. (2016) · Electrochimica Acta · doi:10.1016/j.electacta.2016.10.004 · Cited by 114
In Situ Synthesis of MoP Nanoflakes Intercalated N‐Doped Graphene Nanobelts from MoO3–Amine Hybrid for High‐Efficient Hydrogen Evolution Reaction
Huang, C., Pi, C., Zhang, X., Ding, K., Qin, P. L., Fu, J., Peng, X. F., Gao, B., Chu, P. K.-H., & Huo, K. (2018) · Small · doi:10.1002/smll.201800667 · Cited by 112
Facile synthesis of Fe/Ni bimetallic oxide solid-solution nanoparticles with superior electrocatalytic activity for oxygen evolution reaction
Wang, L., Geng, J., Wang, W., Yuan, C., Kuai, L., & Geng, B. (2015) · Nano Research · doi:10.1007/s12274-015-0881-0 · Cited by 111
Defect-Rich Metallic Titania (TiO1.23)—An Efficient Hydrogen Evolution Catalyst for Electrochemical Water Splitting
Swaminathan, J., Subbiah, R., & Vengatesan, S. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02614 · Cited by 111
Molybdenum sulfide/graphene-carbon nanotube nanocomposite material for electrocatalytic applications in hydrogen evolution reactions
Khan, M., Yousaf, A. B., Chen, M., Wei, C., Wu, X., Huang, N., Qi, Z., & Li, L. (2016) · Nano Research · doi:10.1007/s12274-015-0963-z · Cited by 112
One-pot solvothermal synthesis of Co2P nanoparticles: An efficient HER and OER electrocatalysts
Jebaslinhepzybai, B. T., Partheeban, T., Gavali, D. S., Thapa, R., & Sasidharan, M. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2021.04.022 · Cited by 112
Controlled synthesis of FeP nanorod arrays as highly efficient hydrogen evolution cathode
Liu, R., Gu, S., Du, H., & Li, C. M. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta03638g · Cited by 110
Hollow cobalt phosphide octahedral pre-catalysts with exceptionally high intrinsic catalytic activity for electro-oxidation of water and methanol
Xu, J., Liu, Y., Li, J., Amorim, I., Zhang, B., Xiong, D., Zhang, N., Thalluri, S. M., Sousa, J. P. S., & Liu, L. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta07958g · Cited by 110
Sulfur-Doped CoSe2 Porous Nanosheets as Efficient Electrocatalysts for the Hydrogen Evolution Reaction
Xue, N., Lin, Z., Li, P., Diao, P., & Zhang, Q. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.0c07088 · Cited by 110
Functional Graphdiyne for Emerging Applications: Recent Advances and Future Challenges
Wang, M., Pu, J., Hu, Y., Zi, Y., Wu, Z., & Huang, W. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202308601 · Cited by 111
Pt monolayer coating on complex network substrate with high catalytic activity for the hydrogen evolution reaction
Li, M., Ma, Q., Zi, W., Liu, X., Zhu, X., & Liu, S. F. (2015) · Science Advances · doi:10.1126/sciadv.1400268 · Cited by 110
Aligned MoOx/MoS2 Core–Shell Nanotubular Structures with a High Density of Reactive Sites Based on Self‐Ordered Anodic Molybdenum Oxide Nanotubes
Jin, B., Zhou, X., Huang, L., Licklederer, M., Yang, M., & Schmuki, P. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201605551 · Cited by 109
Photochemical synthesis of CoxP as cocatalyst for boosting photocatalytic H2 production via spatial charge separation
Dong, Y., Kong, L., Wang, G., Jiang, P., Zhao, N., & Zhang, H. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.03.076 · Cited by 108
Structure–Activity Relationships for Pt‐Free Metal Phosphide Hydrogen Evolution Electrocatalysts
Owens‐Baird, B., Kolen’ko, Y. V., & Kovnir, K. A. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201705322 · Cited by 111
Electrochemical Hydrogen Evolution Reaction Efficiently Catalyzed by Ru2P Nanoparticles
Wang, Y., Zong, L., Liu, H., Suen, N., Yu, X., & Feng, L. (2018) · ChemSusChem · doi:10.1002/cssc.201801103 · Cited by 109
FeCoP2 Nanoparticles Embedded in N and P Co-doped Hierarchically Porous Carbon for Efficient Electrocatalytic Water Splitting
Wang, Y., Yang, Z.-J., Yang, D., Li, Z., Shi, X.-R., Yang, G., & Han, B. (2021) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.0c22336 · Cited by 109
Achieving High Electrocatalytic Efficiency on Copper: A Low-Cost Alternative to Platinum for Hydrogen Generation in Water
Zhao, J. F., Tran, P. D., Chen, Y., Loo, S. C. J., Barber, J. P., & Xu, Z. J. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00556 · Cited by 107
Bifunctional CoP and CoN porous nanocatalysts derived from ZIF-67 in situ grown on nanowire photoelectrodes for efficient photoelectrochemical water splitting and CO 2 reduction
Weng, B., Wei, W., Yiliguma, Y., Wu, H., Al‐Enizi, A. M., & Zheng, G. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta06841c · Cited by 107
CoP nanoparticles anchored on N,P-dual-doped graphene-like carbon as a catalyst for water splitting in non-acidic media
Liu, Y., Zhu, Y., Shen, J., Huang, J., Yang, X., & Li, C. (2018) · Nanoscale · doi:10.1039/c7nr07274k · Cited by 108
Templated-preparation of a three-dimensional molybdenum phosphide sponge as a high performance electrode for hydrogen evolution
Deng, C., Ding, F., Li, X., Guo, Y., Ni, W., Yan, H., Sun, K., & Yan, Y. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta05453b · Cited by 108
Designing Efficient Solar‐Driven Hydrogen Evolution Photocathodes Using Semitransparent MoQxCly (Q = S, Se) Catalysts on Si Micropyramids
Ding, Q., Zhai, J., Cabán‐Acevedo, M., Shearer, M. J., Li, L., Chang, H., Tsai, M., Ma, D., Zhang, X., Hamers, R. J., et al. (2015) · Advanced Materials · doi:10.1002/adma.201501884 · Cited by 108
Facile Synthesis of Graphene Sponge from Graphene Oxide for Efficient Dye-Sensitized H2 Evolution
Zhang, W., Li, Y., & Peng, S. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b01805 · Cited by 105
Principles and Methods for the Rational Design of Core–Shell Nanoparticle Catalysts with Ultralow Noble Metal Loadings
Hunt, S. T., & Román‐Leshkov, Y. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.7b00510 · Cited by 105
Electrocatalysts based on metal@carbon core@shell nanocomposites: An overview
Peng, Y., & Chen, S. W. (2018) · Green Energy & Environment · doi:10.1016/j.gee.2018.07.006 · Cited by 105
Electrochemically activated cobalt nickel sulfide for an efficient oxygen evolution reaction: partial amorphization and phase control
Hong, Y.-R., Mhin, S., Kim, K.-M., Han, W., Choi, H., Ali, G., Chung, K. Y., Lee, H. J., Moon, S.-I., Dutta, S., et al. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta10142f · Cited by 106
Unique Catalysis of Nickel Phosphide Nanoparticles to Promote the Selective Transformation of Biofuranic Aldehydes into Diketones in Water
Fujita, S., Nakajima, K., Yamasaki, J., Mizugaki, T., Jitsukawa, K., & Mitsudome, T. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05120 · Cited by 106
RuCo alloy bimodal nanoparticles embedded in N-doped carbon: a superior pH-universal electrocatalyst outperforms benchmark Pt for the hydrogen evolution reaction
Zhang, F., Zhu, Y., Chen, Y., Lu, Y., Lin, Q., Zhang, L., Tao, S., Zhang, X., & Wang, H. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta04491a · Cited by 104
Understanding of the major reactions in solution synthesis of functional nanomaterials
Wu, Y. S., Wang, D. S., & Li, Y. (2016) · Science China Materials · doi:10.1007/s40843-016-5112-0 · Cited by 104
Graphitic C3N4 Decorated with CoP Co‐catalyst: Enhanced and Stable Photocatalytic H2 Evolution Activity from Water under Visible‐light Irradiation
Zhao, H., Jiang, P., & Cai, W. (2016) · Chemistry - An Asian Journal · doi:10.1002/asia.201601543 · Cited by 104
Charge redistribution within platinum–nitrogen coordination structure to boost hydrogen evolution
Cheng, X., Lu, Y., Zheng, L., Cui, Y., Niibe, M., Tokushima, T., Li, H., Zhang, Y., Chen, G., Sun, S., et al. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.104739 · Cited by 105
Ambient Electrosynthesis toward Single‐Atom Sites for Electrocatalytic Green Hydrogen Cycling
Zhao, X. H., He, D., Xia, B. Y., Sun, Y., & You, B. (2023) · Advanced Materials · doi:10.1002/adma.202210703 · Cited by 105
Enhanced electrocatalytic activity of MoP microparticles for hydrogen evolution by grinding and electrochemical activation
Wang, T., Du, K., Liu, W., Zhu, Z., Shao, Y., & Li, M. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta06651k · Cited by 103
Transition metal phosphides: A wonder catalyst for electrocatalytic hydrogen production
Du, M., Li, D., Liu, S. F., & Yan, J. (2023) · Chinese Chemical Letters · doi:10.1016/j.cclet.2023.108156 · Cited by 102
Polyoxometalate‐Derived Ultrasmall Pt2W/WO3 Heterostructure Outperforms Platinum for Large‐Current‐Density H2 Evolution
Peng, Y., Shan, C., Wang, H., Hong, L., Yao, S., Wu, R., Zhang, Z., & Lu, T. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201900597 · Cited by 101
Three-dimensional carbon foam/N-doped graphene@MoS 2 hybrid nanostructures as effective electrocatalysts for the hydrogen evolution reaction
Park, S.-K., Chung, D. Y., Ko, D., Sung, Y.-E., & Piao, Y. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta03458f · Cited by 100
One‐Step Synthesis of Self‐Supported Nickel Phosphide Nanosheet Array Cathodes for Efficient Electrocatalytic Hydrogen Generation
Wang, X., Kolen’ko, Y. V., Bao, X., Kovnir, K. A., & Liu, L. (2015) · Angewandte Chemie · doi:10.1002/ange.201502577 · Cited by 100

Authors: Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E.
Affiliations: Pennsylvania State University (US)
California Institute of Technology (US)
Corresponding author: Lewis, Nathan S.
Schaak, Raymond E.
ORCID: Popczun, Eric J.
Lewis, Nathan S.
Schaak, Raymond E.
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2014-04-11
Volume: 53
Issue: 21
Pages: 5427-5430
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201402646
OpenAlex: W2114572722
Cited by: 1,240
References: 31
Citations by year: 2026: 35 · 2025: 30 · 2024: 59 · 2023: 58 · 2022: 64 · 2021: 99 · 2020: 119 · 2019: 152 · 2018: 141 · 2017: 146 · 2016: 147 · 2015: 142 · 2014: 48
FWCI: 53.04
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
CaltechAUTHORS (California Institute of Technology) (submittedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
Keywords: cobalt phosphide, hydrogen evolution reaction, electrocatalysis, acidic electrocatalysts, sulfuric acid, trioctylphosphine, cobalt nanoparticles, titanium support, earth-abundant catalysts, catalyst stability, hydrogen production

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cites

Cited by

Related

Metadata

Record

About these checks