Amorphous Phosphorus-Incorporated Cobalt Molybdenum Sulfide on Carbon Cloth: An Efficient and Stable Electrocatalyst for Enhanced Overall Water Splitting over Entire pH Values
Abstract
The development of economical, proficient, and highly stable catalysts to substitute the expensive noble metal electrodes for electrocatalytic water-splitting applications is exceedingly desirable. In this context, the most fascinating and challenging approach is the rational design of a nanocomposite encompassing multiple components with unique functionalities. Herein, we describe the fabrication of a strongly catalytic and superb durable phosphorus-incorporated cobalt molybdenum sulfide electrocatalyst grown on carbon cloth (P-CoMoS/CC). The hybrid material exhibited excellent activity for hydrogen and oxygen evolution reactions over a wide range of pH (1-14) with extremely high stability (∼90% retention of the initial current density) after 24 h of electrolysis. Importantly, when P-CoMoS/CC was used as both cathode and anode for overall water splitting, a very low cell voltage of 1.54 V is required to attain the 10 mA cm -2 current density, and the hybrid material exhibited a long-term stability (89.8% activity retention after 100 h). The outstanding overall water-splitting performance compared to an electrolyzer consisting of the noble-metal-based catalysts Pt/C and RuO 2 makes P-CoMoS one of the most efficient earth-abundant water-splitting catalysts. Phosphorus incorporation was proved to be a vital aspect for the improved charge-transfer properties and catalytic durability of the P-CoMoS/CC catalyst.
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Co9S8 is an attractive material for HER because of its good catalytic activity and stability.
“Co9S8 is regarded as an attractive material for HER because of its good catalytic activity and stability [24–33].”
From Synthesis of Au/Co9S8 composite aerogels by one-step sol–gel method as hydrogen evolution reaction electrocatalysts (2021) · cites this paper as [30]
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- Authors
- Ray, C., Lee, S. C., Sankar, K. V., Jin, B., Lee, J., Park, J. H., & Jun, S. C.
- Affiliations
- Yonsei University (KR)
- Corresponding author
- Jun, Seong Chan
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-23
- Volume
- 9
- Issue
- 43
- Pages
- 37739-37749
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2763770968
- Cited by
- 142
- References
- 70
- Citations by year
- 2026: 4 · 2025: 10 · 2024: 12 · 2023: 18 · 2022: 19 · 2021: 20 · 2020: 28 · 2019: 16 · 2018: 15
- FWCI
- 4.33
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Applied Materials & Interfaces (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Ministry of Education, Science and Technology (2009-0093823)
- Ministry of Environment (2016002130005)
- Ministry of Science, ICT and Future Planning (2015R1A5A1037668)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Keywords
- cobalt molybdenum sulfide, phosphorus incorporation, carbon cloth, overall water splitting, hydrogen evolution reaction, oxygen evolution reaction, electrocatalysts, earth-abundant catalysts, charge transfer, catalyst stability, nanocomposites
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