Metal‐Size Influence in Iso‐Selective Lactide Polymerization

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Highly Robust Yttrium Bis(phenolate) Ether Catalysts for Excellent Isoselective Ring-Opening Polymerization of Racemic Lactide

Xu, T., Yang, G., Liu, C., & Lu, X. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02439 · Cited by 93 · see citing works

Biodegradable Polyhydroxyalkanoates by Stereoselective Copolymerization of Racemic Diolides: Stereocontrol and Polyolefin‐Like Properties

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Steric <i>vs.</i> electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes

Ligny, R., Hänninen, M. M., Guillaume, S. M., & Carpentier, J.-F. (2018) · Chemical Communications · doi:10.1039/c8cc03842b · Cited by 88 · see citing works

Self-Switchable Polymerization: A Smart Approach to Sequence-Controlled Degradable Copolymers

Hu, C., Pang, X., & Chen, X. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c00085 · Cited by 87 · see citing works

Highly Isoselective Ring-Opening Polymerization of <i>rac</i> -β-Butyrolactone: Access to Synthetic Poly(3-hydroxybutyrate) with Polyolefin-like Material Properties

Bruckmoser, J., Pongratz, S., Stieglitz, L., & Rieger, B. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c02348 · Cited by 87 · see citing works

Indium Catalysts for Low-Pressure CO2/Epoxide Ring-Opening Copolymerization: Evidence for a Mononuclear Mechanism?

Thevenon, A., Cyriac, A., Myers, D., White, A. J. P., Durr, C. B., & Williams, C. K. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b01920 · Cited by 86 · see citing works

Stereoselective Alkali-Metal Catalysts for Highly Isotactic Poly( rac -lactide) Synthesis

Sun, Y., Xiong, J., Dai, Z., Pan, X., Tang, N., & Wu, J. (2015) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.5b02709 · Cited by 85 · see citing works

Zinc Complexes for PLA Formation and Chemical Recycling: Towards a Circular Economy

McKeown, P., Román‐Ramírez, L. A., Bates, S., Wood, J., & Jones, M. D. (2019) · ChemSusChem · doi:10.1002/cssc.201902755 · Cited by 81 · see citing works

Highly active Mg( ii ) and Zn( ii ) complexes for the ring opening polymerisation of lactide

McKeown, P., McCormick, S. N., Mahon, M. F., & Jones, M. D. (2018) · Polymer Chemistry · doi:10.1039/c8py01369a · Cited by 81 · see citing works

Stereoselective Polymerization of rac-Lactide Catalyzed by Zinc Complexes with Tetradentate Aminophenolate Ligands in Different Coordination Patterns: Kinetics and Mechanism

Yang, Y., Wang, H., & Ma, H. (2015) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.5b00558 · Cited by 79 · see citing works

Highly Syndiotactic or Isotactic Polyhydroxyalkanoates by Ligand-Controlled Yttrium-Catalyzed Stereoselective Ring-Opening Polymerization of Functional Racemic β-Lactones

Ligny, R., Hänninen, M. M., Guillaume, S. M., & Carpentier, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201704283 · Cited by 77 · see citing works

Iso-Selective Ring-Opening Polymerization of rac-Lactide Catalyzed by Crown Ether Complexes of Sodium and Potassium Naphthalenolates

Xiong, J., Zhang, J., Sun, Y., Dai, Z., Pan, X., & Wu, J. (2015) · Inorganic Chemistry · doi:10.1021/ic502685f · Cited by 79 · see citing works

Highly Isoselective and Active Zinc Catalysts for rac-Lactide Polymerization: Effect of Pendant Groups of Aminophenolate Ligands

Kan, C., Hu, J., Huang, Y., Wang, H., & Ma, H. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01420 · Cited by 77 · see citing works

Aluminium salalens vs. salans: “Initiator Design” for the isoselective polymerisation of rac-lactide

McKeown, P., Davidson, M. G., Kociok-Köhn, G. I., & Jones, M. D. (2016) · Chemical Communications · doi:10.1039/c6cc05795k · Cited by 77 · see citing works

La[N(SiMe3)2]3-Catalyzed Ester Reductions with Pinacolborane: Scope and Mechanism of Ester Cleavage

Barger, C. J., Motta, A., Weidner, V. L., Lohr, T. L., & Marks, T. J. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b02605 · Cited by 76 · see citing works

Synthesis of Sodium Complexes Supported with NNO-Tridentate Schiff Base Ligands and Their Applications in the Ring-Opening Polymerization of l -Lactide

Ou, H., Lo, K.-H., Du, W.-T., Lu, W., Chuang, W., Huang, B., Chen, H., & Lin, C. (2016) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.5b02043 · Cited by 75 · see citing works

Cooperative rare earth metal–zinc based heterometallic catalysts for copolymerization of CO 2 and cyclohexene oxide

Qin, J., Xu, B., Zhang, Y., Yuan, D., & Yao, Y. (2016) · Green Chemistry · doi:10.1039/c6gc00511j · Cited by 74 · see citing works

Isoselective Lactide Ring Opening Polymerisation using [2]Rotaxane Catalysts

Lim, J. Y. C., Yuntawattana, N., Beer, P. D., & Williams, C. K. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201901592 · Cited by 71 · see citing works

Alkali-Metal Monophenolates with a Sandwich-Type Catalytic Center as Catalysts for Highly Isoselective Polymerization of rac -Lactide

Dai, Z., Sun, Y., Xiong, J., Pan, X., & Wu, J. (2015) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00209 · Cited by 70 · see citing works

Highly Active Chiral Oxazolinyl Aminophenolate Magnesium Initiators for Isoselective Ring-Opening Polymerization of rac-Lactide: Dinuclearity Induced Enantiomorphic Site Control

Hu, J., Kan, C., Wang, H., & Ma, H. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b00924 · Cited by 68 · see citing works

Aluminum methyl, alkoxide and α-alkoxy ester complexes supported by 6,6′-dimethylbiphenyl-bridged salen ligands: synthesis, characterization and catalysis for rac-lactide polymerization

Kan, C., Ge, J., & Ma, H. (2016) · Dalton Transactions · doi:10.1039/c5dt04633e · Cited by 67 · see citing works

Scandium and Yttrium Phosphasalen Complexes as Initiators for Ring-Opening Polymerization of Cyclic Esters

Bakewell, C., White, A. J. P., Long, N. J., & Williams, C. K. (2015) · Inorganic Chemistry · doi:10.1021/ic5027015 · Cited by 67 · see citing works

Ring opening polymerization of macrolactones: high conversions and activities using an yttrium catalyst

Myers, D., Witt, T., Cyriac, A., Bown, M., Mecking, S., & Williams, C. K. (2017) · Polymer Chemistry · doi:10.1039/c7py00985b · Cited by 70 · see citing works

Isotactic rac‐Lactide Polymerization with Copper Complexes: The Influence of Complex Nuclearity

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Simple sodium and potassium phenolates as catalysts for highly isoselective polymerization of rac-lactide

Dai, Z., Sun, Y., Xiong, J., Pan, X., Tang, N., & Wu, J. (2015) · Catalysis Science & Technology · doi:10.1039/c5cy01194a · Cited by 63 · see citing works

Suppressing Cyclic Polymerization for Isoselective Synthesis of High-Molecular-Weight Linear Polylactide Catalyzed by Sodium/Potassium Sulfonamidate Complexes

Chen, C., Cui, Y., Mao, X., Pan, X., & Wu, J. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b02271 · Cited by 62 · see citing works

Highly Active and Iso‐Selective Catalysts for the Ring‐Opening Polymerization of Cyclic Esters using Group 2 Metal Initiators

Bhattacharjee, J., Harinath, A., Nayek, H. P., Sarkar, A., & Panda, T. K. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201700672 · Cited by 59 · see citing works

Reactivity and Properties of Metal Complexes Enabled by Flexible and Redox-Active Ligands with a Ferrocene Backbone

Huang, W., & Diaconescu, P. L. (2016) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.6b01118 · Cited by 56 · see citing works

Stereoselective Lactide Polymerization: the Challenge of Chiral Catalyst Recognition

D’Alterio, M. C., Rosa, C. D., & Talarico, G. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05109 · Cited by 54 · see citing works

The role of neutral donor ligands in the isoselective ring-opening polymerization of rac -β-butyrolactone

Dong, X., & Robinson, J. R. (2020) · Chemical Science · doi:10.1039/d0sc03507f · Cited by 50 · see citing works

Exploring Steric Effects in Diastereoselective Synthesis of Chiral Aminophenolate Zinc Complexes and Stereoselective Ring-Opening Polymerization of <i>rac</i>-Lactide

Wang, H., Yang, Y., & Ma, H. (2016) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.6b00378 · Cited by 50 · see citing works

Bimetallic aluminum complexes with cyclic β-ketiminato ligands: the cooperative effect improves their capability in polymerization of lactide and ε-caprolactone

Huang, H.-C., Wang, B., Zhang, Y.-P., & Li, Y.-S. (2016) · Polymer Chemistry · doi:10.1039/c6py01092j · Cited by 49 · see citing works

Di‐Zinc–Aryl Complexes: CO2 Insertions and Applications in Polymerisation Catalysis

Romain, C., Garden, J. A., Trott, G., Buchard, A., White, A. J. P., & Williams, C. K. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201701013 · Cited by 48 · see citing works

Mechanistic Investigations of the Stereoselective Rare Earth Metal-Mediated Ring-Opening Polymerization of β-Butyrolactone

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Gallium and indium complexes containing the bis(imino)phenoxide ligand: synthesis, structural characterization and polymerization studies

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Diastereoselective synthesis of chiral aminophenolate magnesium complexes and their application in the stereoselective polymerization of rac-lactide and rac-β-butyrolactone

Wang, H., Guo, J., Yang, Y., & Ma, H. (2016) · Dalton Transactions · doi:10.1039/c6dt01126h · Cited by 45 · see citing works

Synthesis and Characterization of Yttrium and Ytterbium Complexes Supported by Salen Ligands and Their Catalytic Properties for rac-Lactide Polymerization

Gu, W., Xu, P., Wang, Y., Yao, Y., Yuan, D., & Shen, Q. (2015) · Organometallics · doi:10.1021/acs.organomet.5b00223 · Cited by 45 · see citing works

Dialkylgallium Alkoxides Stabilized with N-Heterocyclic Carbenes: Opportunities and Limitations for the Controlled and Stereoselective Polymerization of rac-Lactide

Horeglad, P., Cybularczyk‐Cecotka, M., Trzaskowski, B., Żukowska, G. Z., Dranka, M., & Zachara, J. (2015) · Organometallics · doi:10.1021/acs.organomet.5b00071 · Cited by 43 · see citing works

Isoselective mechanism of the ring-opening polymerization of rac-lactide catalyzed by chiral potassium binolates

Cui, Y., Chen, C., Sun, Y., Wu, J., & Pan, X. (2016) · Inorganic Chemistry Frontiers · doi:10.1039/c6qi00449k · Cited by 44 · see citing works

Ring Opening Polymerization and Copolymerization of Cyclic Esters Catalyzed by Group 2 Metal Complexes Supported by Functionalized P–N Ligands

Harinath, A., Bhattacharjee, J., Sarkar, A., Nayek, H. P., & Panda, T. K. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b02847 · Cited by 42 · see citing works

Isoselective Polymerization of rac-Lactide Catalyzed by Ion-Paired Potassium Amidinate Complexes

Chen, C., Jiang, J., Mao, X., Cong, Y., Cui, Y., Pan, X., & Wu, J. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b03184 · Cited by 42 · see citing works

Tuning the Thiolen: Al(III) and Fe(III) Thiolen Complexes for the Isoselective ROP of <i>rac</i>-Lactide

Stewart, J. A., McKeown, P., Driscoll, O. J., Mahon, M. F., Ward, B. D., & Jones, M. D. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b01205 · Cited by 40 · see citing works

Synthesis and characterization of rare-earth metal complexes supported by a new pentadentate Schiff base and their application in heteroselective polymerization of rac-lactide

Cui, Y. N., Gu, W., Wang, Y., Zhao, B., Yao, Y., & Shen, Q. (2015) · Catalysis Science & Technology · doi:10.1039/c5cy00322a · Cited by 40 · see citing works

Different mechanisms at different temperatures for the ring-opening polymerization of lactide catalyzed by binuclear magnesium and zinc alkoxides

Sun, Y., Cui, Y., Xiong, J., Dai, Z., Tang, N., & Wu, J. (2015) · Dalton Transactions · doi:10.1039/c5dt01784j · Cited by 39 · see citing works

Group 4 Metal Complexes of Phenylene–Salalen Ligands in rac‐Lactide Polymerization Giving High Molecular Weight Stereoblock Poly(lactic acid)

Stopper, A., Rosen, T., Venditto, V., Goldberg, I., & Kol, M. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201701007 · Cited by 38 · see citing works

Mononuclear Salen–Sodium Ion Pairs as Catalysts for Isoselective Polymerization of rac -Lactide

Cui, Y., Jiang, J., Mao, X., & Wu, J. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.8b02290 · Cited by 37 · see citing works

Syntheses and chemical transformations of glycolide and lactide as monomers for biodegradable polymers

Botvin, V. V., Karaseva, S., Salikova, D., & Dusselier, M. (2020) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2020.109427 · Cited by 38 · see citing works

Group 4 complexes of salicylbenzoxazole ligands as effective catalysts for the ring-opening polymerization of lactides, epoxides and copolymerization of ε-caprolactone with L-lactide

Pappuru, S., Chakraborty, D., Sundar, J. V., Roymuhury, S. K., Ramkumar, V., Subramanian, V., & Chand, D. K. (2016) · Polymer · doi:10.1016/j.polymer.2016.08.007 · Cited by 36 · see citing works

Zinc Chloride Complexes with Aliphatic and Aromatic Guanidine Hybrid Ligands and Their Activity in the Ring‐Opening Polymerisation of d,l ‐Lactide

Metz, A., Plothe, R., Glowacki, B., Koszalkowski, A., Scheckenbach, M., Beringer, A., Rösener, T., Vasconcellos, J. M. D., Haase, R., Flörke, Ü., et al. (2016) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201600870 · Cited by 35 · see citing works

Indium phosphasalen catalysts showing high isoselectivity and activity in racemic lactide and lactone ring opening polymerizations

Yuntawattana, N., McGuire, T. M., Durr, C. B., Buchard, A., & Williams, C. K. (2020) · Catalysis Science &amp; Technology · doi:10.1039/d0cy01484b · Cited by 35 · see citing works

Synthesis and Characterization of Dinuclear Salan Rare-Earth Metal Complexes and Their Application in the Homo- and Copolymerization of Cyclic Esters

Ouyang, H., Yuan, D., Nie, K., Zhang, Y., Yao, Y., & Cui, D. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.8b01046 · Cited by 34 · see citing works

Lanthanum complexes containing a bis(phenolate) ligand with a ferrocene-1,1′-diyldithio backbone: synthesis, characterization, and ring-opening polymerization of rac-lactide

Hermans, C., Rong, W., Spaniol, T. P., & Okuda, J. (2016) · Dalton Transactions · doi:10.1039/c6dt00272b · Cited by 33 · see citing works

Zirconium vs Aluminum Salalen Initiators for the Production of Biopolymers

Kirk, S. M., Kociok-Köhn, G. I., & Jones, M. D. (2016) · Organometallics · doi:10.1021/acs.organomet.6b00718 · Cited by 33 · see citing works

Iron(III) Salalen Complexes for the Polymerisation of Lactide

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Ligands and complexes based on piperidine and their exploitation of the ring opening polymerisation of rac-lactide

McKeown, P., Brown-Humes, J., Davidson, M. G., Mahon, M. F., Woodman, T. J., & Jones, M. D. (2017) · Dalton Transactions · doi:10.1039/c7dt00751e · Cited by 32 · see citing works

Aluminum Complexes of Monopyrrolidine Ligands for the Controlled Ring-Opening Polymerization of Lactide

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Aluminium complexes containing salicylbenzothiazole ligands and their application in the ring-opening polymerisation of rac-lactide and ε-caprolactone

Nakonkhet, C., Nanok, T., Wattanathana, W., Chuawong, P., & Hormnirun, P. (2017) · Dalton Transactions · doi:10.1039/c7dt02435e · Cited by 31 · see citing works

Controlling the stereoselectivity of rac-LA polymerization by chiral recognition induced the formation of homochiral dimeric metal alkoxides

Horeglad, P., Cybularczyk‐Cecotka, M., Litwińska, A., Dąbrowska, A. M., Dranka, M., Żukowska, G. Z., Urbańczyk, M., & Michalak, M. (2016) · Polymer Chemistry · doi:10.1039/c5py02005k · Cited by 31 · see citing works

(Benz)Imidazolin-2-iminato Aluminum, Zinc, and Magnesium Complexes and Their Applications in Ring Opening Polymerization of ε-Caprolactone

Liu, H., Khononov, M., Fridman, N., Tamm, M., & Eisen, M. S. (2019) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.9b02324 · Cited by 31 · see citing works

Heterolepic β ‐Ketoiminate Zinc Phenoxide Complexes as Efficient Catalysts for the Ring Opening Polymerization of Lactide

Ghosh, S., Schäfer, P. M., Dittrich, D., Scheiper, C., Steiniger, P., Fink, G., Ksiazkiewicz, A. N., Tjaberings, A., Wölper, C., Gröschel, A. H., et al. (2019) · ChemistryOpen · doi:10.1002/open.201900203 · Cited by 30 · see citing works

Dizinc Lactide Polymerization Catalysts: Hyperactivity by Control of Ligand Conformation and Metallic Cooperativity

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Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization of rac-lactide and rac-β-butyrolactone

Zeng, T., Qian, Q., Zhao, B., Yuan, D., Yao, Y., & Shen, Q. (2015) · RSC Advances · doi:10.1039/c5ra10151d · Cited by 29 · see citing works

Magnesium and zinc complexes bearing NNO-tridentate ketiminate ligands: synthesis, structures and catalysis in the ring-opening polymerization of lactides

Huang, Y., Kou, X., Duan, Y.-L., Ding, F.-F., Yin, Y., Wang, W., & Yang, Y. (2018) · Dalton Transactions · doi:10.1039/c8dt00888d · Cited by 29 · see citing works

Exploring Steric Effects of Zinc Complexes Bearing Achiral Benzoxazolyl Aminophenolate Ligands in Isoselective Polymerization of rac-Lactide

Hu, J., Kan, C., & Ma, H. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.8b01839 · Cited by 28 · see citing works

ZnII Chlorido Complexes with Aliphatic, Chiral Bisguanidine Ligands as Catalysts in the Ring‐Opening Polymerisation of rac‐Lactide Using FT‐IR Spectroscopy in Bulk

Metz, A., McKeown, P., Eßer, B., Gohlke, C., Kröckert, K. W., Laurini, L., Scheckenbach, M., McCormick, S. N., Oswald, M., Hoffmann, A., et al. (2017) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201701147 · Cited by 27 · see citing works

Stereoselective polymerization of rac -lactide catalyzed by zwitterionic calcium complexes

Liu, N., Liu, D., Liu, B., Zhang, H., & Cui, D. (2020) · Polymer Chemistry · doi:10.1039/d0py01397h · Cited by 27 · see citing works

Structurally Characterized Lead(II) Alkoxides as Potent Ring-Opening Polymerization Catalysts

Wang, L., Fadlallah, S., Bellini, C., Orione, C., Dorcet, V., Carpentier, J., & Sarazin, Y. (2015) · Organometallics · doi:10.1021/acs.organomet.5b00052 · Cited by 27 · see citing works

Aminopiperidine based complexes for lactide polymerisation

McKeown, P., Davidson, M. G., Lowe, J. P., Mahon, M. F., Thomas, L. H., Woodman, T. J., & Jones, M. D. (2016) · Dalton Transactions · doi:10.1039/c5dt04695e · Cited by 25 · see citing works

Salan group 13 complexes – structural study and lactide polymerisation

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Stereoselective ring-opening polymerization of functional β-lactones: influence of the exocyclic side-group

Shakaroun, R. M., Li, H., Jéhan, P., Blot, M., Alaaeddine, A., Carpentier, J.-F., & Guillaume, S. M. (2021) · Polymer Chemistry · doi:10.1039/d1py00669j · Cited by 25 · see citing works

Ring Opening Polymerization of Six- and Eight-Membered Racemic Cyclic Esters for Biodegradable Materials

Grillo, A., Rusconi, Y., D’Alterio, M. C., Rosa, C. D., Talarico, G., & Poater, A. (2024) · International Journal of Molecular Sciences · doi:10.3390/ijms25031647 · Cited by 25 · see citing works

Copolymer of lactide and ε-caprolactone catalyzed by bimetallic Schiff base aluminum complexes

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Isoselective Lactide Ring Opening Polymerisation using [2]Rotaxane Catalysts

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Synthesis and characterization of dinuclear rare-earth complexes supported by amine-bridged bis(phenolate) ligands and their catalytic activity for the ring-opening polymerization of l -lactide

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Phosphasalen Indium Complexes Showing High Rates and Isoselectivities in rac‐Lactide Polymerizations

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High performance benzoimidazolyl-based aminophenolate zinc complexes for isoselective polymerization of rac -lactide

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The metal role on the activity and stereoselectivity of ring opening polymerization of racemic lactide promoted by Salen catalysts

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Phosphasalalen Rare-Earth Complexes for the Polymerization of rac-Lactide and rac-β-Butyrolactone

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Alkali metal complex-mediated ring-opening polymerization of rac -LA, ε-caprolactone, and δ-valerolactone

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Squeezing Bi: PNP and P 2 N 3 pincer complexes of bismuth

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Highly Isoselective Ring‐Opening Polymerization of rac‐Lactide Using Chiral Binuclear Aluminum Catalyst

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Highly Robust Yttrium Bis(phenolate) Ether Catalysts for Excellent Isoselective Ring-Opening Polymerization of Racemic Lactide

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Stereoselective Alkali-Metal Catalysts for Highly Isotactic Poly( rac -lactide) Synthesis

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