Iron(III) Salalen Complexes for the Polymerisation of Lactide
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Herein, we report the preparation and characterisation of iron(III) salalen complexes, with variation of ligand substituents and backbone investigated. Six new complexes were prepared and characterised by elemental analysis, mass spectrometry and X‐ray crystallography. These complexes have been applied for the ring opening polymerisation (ROP) of rac‐lactide in propylene oxide. Fe(1)Cl was found to have a moderate isotactic preference (P m = 0.75–0.80) and demonstrated good molecular weight control in solution (Đ = 1.02–1.18). Fe(2–7)Cl were also active for ROP and activities could be related to ligand structure.
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- Driscoll, O., Leung, C., McKeown, P., Mahon, M., & Jones, M. (2018). Iron (III) Salalen Complexes for the Polymerisation of Lactide. European Journal of Inorganic Chemistry, 2018(47), 5129-5135. https://doi.org/10.1002/ejic.201801239
- Iron (III) Salalen Complexes for the Polymerisation of Lactide. / Driscoll, Oliver; Leung, Chris ; McKeown, Paul et al. In: European Journal of Inorganic Chemistry, Vol. 2018, No. 47, 19.12.2018, p. 5129-5135.
- Driscoll, O, Leung, C, McKeown, P, Mahon, M & Jones, M 2018, 'Iron (III) Salalen Complexes for the Polymerisation of Lactide' European Journal of Inorganic Chemistry, vol. 2018, no. 47, pp. 5129-5135. https://doi.org/10.1002/ejic.201801239
- Driscoll O, Leung C, McKeown P, Mahon M, Jones M. Iron (III) Salalen Complexes for the Polymerisation of Lactide. European Journal of Inorganic Chemistry. 2018 Dec 19;2018(47):5129-5135. Epub 2018 Dec 5. doi: 10.1002/ejic.201801239
- Driscoll, Oliver ; Leung, Chris ; McKeown, Paul et al. / Iron (III) Salalen Complexes for the Polymerisation of Lactide. In: European Journal of Inorganic Chemistry. 2018 ; Vol. 2018, No. 47. pp. 5129-5135.
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Nachtaktiv: Eisen‐Guanidin‐Komplex katalysiert ROP auf der schlafenden Seite der ATRP
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- Authors
- Driscoll, O. J., Leung, C. K. C., Mahon, M. F., McKeown, P., & Jones, M. D.
- Affiliations
- University of Bath (GB)
- Corresponding author
- Jones, Matthew D.
- Venue
- European Journal of Inorganic Chemistry
- Publisher
- Wiley
- Published
- 2018-12-05
- Volume
- 2018
- Issue
- 47
- Pages
- 5129-5135
- ISSN
- 1099-0682 (ISSN-L)
- 1434-1948
- OpenAlex
- W2899712433
- Cited by
- 32
- References
- 82
- Citations by year
- 2026: 1 · 2025: 3 · 2024: 1 · 2023: 6 · 2022: 5 · 2021: 5 · 2020: 3 · 2019: 8
- FWCI
- 1.30
- Type
- journal article
- Language
- en
- Open access
- Licence
- Locations
- European Journal of Inorganic Chemistry (publishedVersion)
- Pure (University of Bath) (submittedVersion, other-oa)
- Funders
- Engineering and Physical Sciences Research Council (EP/P016405/1)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- ring-opening polymerization, lactide, propylene oxide, isotacticity, molecular weight control, ligand substituent effects, polycaprolactone, polypropylene glycol
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