Cited by 32biodegradable polymer synthesis and propertiesOrganometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysis

Iron(III) Salalen Complexes for the Polymerisation of Lactide

Open access
Driscoll, Oliver J., Leung, Christopher K. C., Mahon, Mary F., McKeown, Paul, Jones, Matthew D.·2018·European Journal of Inorganic Chemistry

Abstract

Herein, we report the preparation and characterisation of iron(III) salalen complexes, with variation of ligand substituents and backbone investigated. Six new complexes were prepared and characterised by elemental analysis, mass spectrometry and X‐ray crystallography. These complexes have been applied for the ring opening polymerisation (ROP) of rac‐lactide in propylene oxide. Fe(1)Cl was found to have a moderate isotactic preference (P m = 0.75–0.80) and demonstrated good molecular weight control in solution (Đ = 1.02–1.18). Fe(2–7)Cl were also active for ROP and activities could be related to ligand structure.

Integrity signals

Registry

Crossref · 10.1002/ejic.201801239

Cites

81 of 81 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

The text we found for this paper looks like another document, so its claims and self-check weren’t run. The registry and citation checks still apply.

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The text we found for this paper looks like another document, so the self-check wasn’t run.

Cites

Flagged first, then by citations

1 of the 82 references couldn’t be matched to a known paper.

Research works printed but not linked: 5

  1. Driscoll, O., Leung, C., McKeown, P., Mahon, M., & Jones, M. (2018). Iron (III) Salalen Complexes for the Polymerisation of Lactide. European Journal of Inorganic Chemistry, 2018(47), 5129-5135. https://doi.org/10.1002/ejic.201801239
  2. Iron (III) Salalen Complexes for the Polymerisation of Lactide. / Driscoll, Oliver; Leung, Chris ; McKeown, Paul et al. In: European Journal of Inorganic Chemistry, Vol. 2018, No. 47, 19.12.2018, p. 5129-5135.
  3. Driscoll, O, Leung, C, McKeown, P, Mahon, M & Jones, M 2018, 'Iron (III) Salalen Complexes for the Polymerisation of Lactide' European Journal of Inorganic Chemistry, vol. 2018, no. 47, pp. 5129-5135. https://doi.org/10.1002/ejic.201801239
  4. Driscoll O, Leung C, McKeown P, Mahon M, Jones M. Iron (III) Salalen Complexes for the Polymerisation of Lactide. European Journal of Inorganic Chemistry. 2018 Dec 19;2018(47):5129-5135. Epub 2018 Dec 5. doi: 10.1002/ejic.201801239
  5. Driscoll, Oliver ; Leung, Chris ; McKeown, Paul et al. / Iron (III) Salalen Complexes for the Polymerisation of Lactide. In: European Journal of Inorganic Chemistry. 2018 ; Vol. 2018, No. 47. pp. 5129-5135.

Cited by

Sorted by citations

Authors
Driscoll, O. J., Leung, C. K. C., Mahon, M. F., McKeown, P., & Jones, M. D.
Affiliations
University of Bath (GB)
Corresponding author
Jones, Matthew D.
Venue
European Journal of Inorganic Chemistry
Publisher
Wiley
Published
2018-12-05
Volume
2018
Issue
47
Pages
5129-5135
ISSN
  • 1099-0682 (ISSN-L)
  • 1434-1948
OpenAlex
W2899712433
Cited by
32
References
82
Citations by year
2026: 1 · 2025: 3 · 2024: 1 · 2023: 6 · 2022: 5 · 2021: 5 · 2020: 3 · 2019: 8
FWCI
1.30
Type
journal article
Language
en
Locations
  • European Journal of Inorganic Chemistry (publishedVersion)
  • Pure (University of Bath) (submittedVersion, other-oa)
Funders
Engineering and Physical Sciences Research Council (EP/P016405/1)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
  • Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
Keywords
ring-opening polymerization, lactide, propylene oxide, isotacticity, molecular weight control, ligand substituent effects, polycaprolactone, polypropylene glycol

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review