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Cited by 325

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Hierarchical Zn/Ni‐MOF‐2 Nanosheet‐Assembled Hollow Nanocubes for Multicomponent Catalytic Reactions

Zhang, Zhicheng, Chen, Yifeng, He, Su, Zhang, Jingchao, Xu, Xiaobin, Yang, Yong, Nosheen, Farhat, Saleem, Faisal, He, Wei, Wang, Xun·2014·Angewandte Chemie International Edition

Abstract

Metal‐organic frameworks (MOFs) are potentially useful molecular materials that can exhibit structure flexibilities induced by some external stimuli. Such structure transformations can furnish MOFs with improved properties. The shape‐controlled growth of MOFs combined with crystal‐structure transformation is rarely achieved. Herein, we demonstrate the synthesis of hierarchical Zn/Ni‐MOF‐2 nanosheet‐assembled hollow nanocubes (NAHNs) by a facile surfactant‐free solvothermal approach. The unique nanostructures undergo crystal‐structure transformation from Zn/Ni‐MOF‐5 nanocubes to Zn/Ni‐MOF‐2 nanosheets, which is analogous to the dissolution and recrystallization of inorganic nanocrystals. The present synthetic strategy to fabricate isostructural MOFs with hierarchical, hollow, and bimetallic nanostructures is expected to expand the diversity and range of potential applications of MOFs.

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Metadata

Authors
Zhang, Z., Chen, Y., He, S., Zhang, J., Xu, X., Yang, Y., Nosheen, F., Saleem, F., He, W., & Wang, X.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2014-07-27
Volume
53
Issue
46
Pages
12517-12521
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2165206351
Cited by
325
References
1
FWCI
11.57
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Hierarchical Zn/Ni‐MOF‐2 Nanosheet‐Assembled Hollow Nanocubes for Multicomponent Catalytic Reactions. https://app.cochat.ai/papers/10.1002/anie.201406484
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Zhang, Z., Chen, Y., He, S., Zhang, J., Xu, X., Yang, Y., Nosheen, F., Saleem, F., He, W., & Wang, X. (2014). Hierarchical Zn/Ni‐MOF‐2 Nanosheet‐Assembled Hollow Nanocubes for Multicomponent Catalytic Reactions. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201406484

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