The DOI matches its Crossref record; 46 of the 46 references it cites were found in a registry or an index.
Multi‐shelled Hollow Metal–Organic Frameworks
Abstract
Hollow metal–organic frameworks (MOFs) are promising materials with sophisticated structures, such as multiple shells, that cannot only enhance the properties of MOFs but also endow them with new functions. Herein, we show a rational strategy to fabricate multi‐shelled hollow chromium (III) terephthalate MOFs (MIL‐101) with single‐crystalline shells through step‐by‐step crystal growth and subsequent etching processes. This strategy relies on the creation of inhomogeneous MOF crystals in which the outer layer is chemically more robust than the inner layer and can be selectively etched by acetic acid. The regulation of MOF nucleation and crystallization allows the tailoring of the cavity size and shell thickness of each layer. The resultant multi‐shelled hollow MIL‐101 crystals show significantly enhanced catalytic activity during styrene oxidation. The insight gained from this systematic study will aid in the rational design and synthesis of other multi‐shelled hollow structures and the further expansion of their applications.
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Cites
Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200802248 · Cited by 5,702
A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
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Hydrogen Storage in Microporous Metal-Organic Frameworks
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Self-citationBioMOFs: Metal–Organic Frameworks for Biological and Medical Applications
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Cited by
MOF-derived nanohybrids for electrocatalysis and energy storage: current status and perspectives
Zhang, H., Liu, X., Wu, Y., Guan, C., Cheetham, A. K., & Wang, J. (2018) · Chemical Communications · doi:10.1039/c8cc00789f · Cited by 309
Metadata
- Authors
- Liu, W., Huang, J., Yang, Q., Wang, S., Sun, X., Zhang, W., Liu, J., & Huo, F.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-03-23
- Volume
- 56
- Issue
- 20
- Pages
- 5512-5516
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2599511907
- Cited by
- 367
- References
- 46
- FWCI
- 14.51
- Type
- journal article
- Language
- en
- Open access
- closed
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