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Chemical and Structural Stability of Zirconium‐based Metal–Organic Frameworks with Large Three‐Dimensional Pores by Linker Engineering

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Kalidindi, Suresh B., Nayak, Sanjit, Briggs, Michael E., Jansat, Susanna, Katsoulidis, Alexandros P., Miller, Gary J., Warren, John E., Antypov, Dmytro, Corà, Furio, Slater, Ben, Prestly, Mark R., Martí‐Gastaldo, Carlos, Rosseinsky, Matthew J.·2015·Angewandte Chemie International Edition

Abstract

The synthesis of metal–organic frameworks with large three‐dimensional channels that are permanently porous and chemically stable offers new opportunities in areas such as catalysis and separation. Two linkers (L1=4,4′,4′′,4′′′‐([1,1′‐biphenyl]‐3,3′,5,5′‐tetrayltetrakis(ethyne‐2,1‐diyl)) tetrabenzoic acid, L2=4,4′,4′′,4′′′‐(pyrene‐1,3,6,8‐tetrayltetrakis(ethyne‐2,1‐diyl))tetrabenzoic acid) were used that have equivalent connectivity and dimensions but quite distinct torsional flexibility. With these, a solid solution material, [Zr 6 O 4(OH)4(L1)2.6(L2)0.4]⋅(solvent)x, was formed that has three‐dimensional crystalline permanent porosity with a surface area of over 4000 m 2 g−1 that persists after immersion in water. These properties are not accessible for the isostructural phases made from the separate single linkers.

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Metadata

Authors
Kalidindi, S. B., Nayak, S., Briggs, M. E., Jansat, S., Katsoulidis, A. P., Miller, G. J., Warren, J. E., Antypov, D., Corà, F., Slater, B., Prestly, M. R., Martí‐Gastaldo, C., & Rosseinsky, M. J.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2014-12-17
Volume
54
Issue
1
Pages
221-226
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2162455674
Cited by
170
References
2
FWCI
7.62
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Chemical and Structural Stability of Zirconium‐based Metal–Organic Frameworks with Large Three‐Dimensional Pores by Linker Engineering. https://app.cochat.ai/papers/10.1002/anie.201406501
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Kalidindi, S. B., Nayak, S., Briggs, M. E., Jansat, S., Katsoulidis, A. P., Miller, G. J., Warren, J. E., Antypov, D., Corà, F., Slater, B., Prestly, M. R., Martí‐Gastaldo, C., & Rosseinsky, M. J. (2015). Chemical and Structural Stability of Zirconium‐based Metal–Organic Frameworks with Large Three‐Dimensional Pores by Linker Engineering. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201406501

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