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Molybdenum Phosphosulfide: An Active, Acid‐Stable, Earth‐Abundant Catalyst for the Hydrogen Evolution Reaction
Abstract
Introducing sulfur into the surface of molybdenum phosphide (MoP) produces a molybdenum phosphosulfide (MoP|S) catalyst with superb activity and stability for the hydrogen evolution reaction (HER) in acidic environments. The MoP|S catalyst reported herein exhibits one of the highest HER activities of any non-noble-metal electrocatalyst investigated in strong acid, while remaining perfectly stable in accelerated durability testing. Whereas mixed-metal alloy catalysts are well-known, MoP|S represents a more uncommon mixed-anion catalyst where synergistic effects between sulfur and phosphorus produce a high-surface-area electrode that is more active than those based on either the pure sulfide or the pure phosphide. The extraordinarily high activity and stability of this catalyst open up avenues to replace platinum in technologies relevant to renewable energies, such as proton exchange membrane (PEM) electrolyzers and solar photoelectrochemical (PEC) water-splitting cells.
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“the Cdl values (Fig. 4d) of N-Rh/CA, Rh/CA and CA were calculated as 30.84 mF cm− 2, 6.01 mF cm− 2, 1.41 mF cm− 2, respectively, which are in direct proportion to ECSA [42].”
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Combining theory and experiment in electrocatalysis: Insights into materials design
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Metadata
- Authors
- Kibsgaard, J., & Jaramillo, T. F.
- Affiliations
- Stanford University (US)
- Corresponding author
- Jaramillo, Thomas F.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-10-30
- Volume
- 53
- Issue
- 52
- Pages
- 14433-14437
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2167228022
- Cited by
- 1,048
- References
- 32
- Citations by year
- 2026: 31 · 2025: 47 · 2024: 62 · 2023: 71 · 2022: 83 · 2021: 103 · 2020: 121 · 2019: 145 · 2018: 132 · 2017: 111 · 2016: 87 · 2015: 52 · 2014: 1
- FWCI
- 27.53
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Keywords
- hydrogen evolution reaction, electrocatalysts, acid stability, non-noble metal catalysts, accelerated durability testing, proton exchange membrane electrolyzer, platinum-free catalysts
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