The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Molybdenum Phosphosulfide: An Active, Acid‐Stable, Earth‐Abundant Catalyst for the Hydrogen Evolution Reaction
Abstract
Introducing sulfur into the surface of molybdenum phosphide (MoP) produces a molybdenum phosphosulfide (MoP|S) catalyst with superb activity and stability for the hydrogen evolution reaction (HER) in acidic environments. The MoP|S catalyst reported herein exhibits one of the highest HER activities of any non-noble-metal electrocatalyst investigated in strong acid, while remaining perfectly stable in accelerated durability testing. Whereas mixed-metal alloy catalysts are well-known, MoP|S represents a more uncommon mixed-anion catalyst where synergistic effects between sulfur and phosphorus produce a high-surface-area electrode that is more active than those based on either the pure sulfide or the pure phosphide. The extraordinarily high activity and stability of this catalyst open up avenues to replace platinum in technologies relevant to renewable energies, such as proton exchange membrane (PEM) electrolyzers and solar photoelectrochemical (PEC) water-splitting cells.
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“the Cdl values (Fig. 4d) of N-Rh/CA, Rh/CA and CA were calculated as 30.84 mF cm− 2, 6.01 mF cm− 2, 1.41 mF cm− 2, respectively, which are in direct proportion to ECSA [42].”
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Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Self-citationMoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Self-citationSolar Energy Supply and Storage for the Legacy and Nonlegacy Worlds
Cook, T. R., Dogutan, D. K., Reece, S. Y., Surendranath, Y., Teets, T. S., & Nocera, D. G. (2010) · Chemical Reviews · doi:10.1021/cr100246c · Cited by 3,102
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
Morales-Guio, C. G., Stern, L.-A., & Hu, X. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60468c · Cited by 2,437
Catalyzing the hydrogen evolution reaction (HER) with molybdenum sulfide nanomaterials
Benck, J. D., Hellstern, T. R., Kibsgaard, J., Chakthranont, P., & Jaramillo, T. F. (2014) · ACS Catalysis · doi:10.1021/cs500923c · Cited by 1,617
Self-citationMolybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction
Xiao, P., Sk, M. A., Thia, L., Ge, X., Lim, R. J., Wang, J.-Y., Lim, K. H., & Wang, X. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee00957f · Cited by 1,297
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Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Self-citationNoble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Shinagawa, T., Garcia-Esparza, A. T., & Takanabe, K. (2015) · Scientific Reports · doi:10.1038/srep13801 · Cited by 3,287
Shi, Y., & Zhang, B. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00434a · Cited by 3,253
Metadata
- Authors
- Kibsgaard, J., & Jaramillo, T. F.
- Affiliations
- Stanford University (US)
- Corresponding author
- Jaramillo, Thomas F.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-10-30
- Volume
- 53
- Issue
- 52
- Pages
- 14433-14437
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2167228022
- Cited by
- 1,048
- References
- 32
- Citations by year
- 2026: 31 · 2025: 47 · 2024: 62 · 2023: 71 · 2022: 83 · 2021: 103 · 2020: 121 · 2019: 145 · 2018: 132 · 2017: 111 · 2016: 87 · 2015: 52 · 2014: 1
- FWCI
- 27.53
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Keywords
- hydrogen evolution reaction, electrocatalysts, acid stability, non-noble metal catalysts, accelerated durability testing, proton exchange membrane electrolyzer, platinum-free catalysts
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