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Ruthenium‐Catalyzed CC Bond Cleavage in Lignin Model Substrates

vom Stein, Thorsten, den Hartog, Tim, Buendia, Julien, Stoychev, Spas, Mottweiler, Jakob, Bolm, Carsten, Klankermayer, Jürgen, Leitner, Walter·2015·Angewandte Chemie International Edition

Abstract

Ruthenium–triphos complexes exhibited unprecedented catalytic activity and selectivity in the redox‐neutral CC bond cleavage of the β‐O‐4 lignin linkage of 1,3‐dilignol model compounds. A mechanistic pathway involving a dehydrogenation‐initiated retro‐aldol reaction for the CC bond cleavage was proposed in line with experimental data and DFT calculations.

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Metadata

Authors
vom Stein, T., den Hartog, T., Buendia, J., Stoychev, S., Mottweiler, J., Bolm, C., Klankermayer, J., & Leitner, W.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2015-03-25
Volume
54
Issue
20
Pages
5859-5863
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2143555046
Cited by
162
References
3
FWCI
9.75
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Ruthenium‐Catalyzed CC Bond Cleavage in Lignin Model Substrates. https://app.cochat.ai/papers/10.1002/anie.201410620
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vom Stein, T., den Hartog, T., Buendia, J., Stoychev, S., Mottweiler, J., Bolm, C., Klankermayer, J., & Leitner, W. (2015). Ruthenium‐Catalyzed CC Bond Cleavage in Lignin Model Substrates. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201410620

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.