The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Cationic RAFT Polymerization Using ppm Concentrations of Organic Acid
Abstract
A metal‐free, cationic, reversible addition–fragmentation chain‐transfer (RAFT) polymerization was proposed and realized. A series of thiocarbonylthio compounds were used in the presence of a small amount of triflic acid for isobutyl vinyl ether to give polymers with controlled molecular weight of up to 1×10 5 and narrow molecular‐weight distributions (M w/M n<1.1). This “living” or controlled cationic polymerization is applicable to various electron‐rich monomers including vinyl ethers, p‐methoxystyrene, and even p‐hydroxystyrene that possesses an unprotected phenol group. A transformation from cationic to radical RAFT polymerization enables the synthesis of block copolymers between cationically and radically polymerizable monomers, such as vinyl ether and vinyl acetate or methyl acrylate.
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Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622
Kato, M., Kamigaito, M., Sawamoto, M., & Higashimura, T. (1995) · Macromolecules · doi:10.1021/ma00109a056 · Cited by 3,046
Self-citationRadical chemistry associated with the thiocarbonyl group
Crich, D., & Quintero, L. (1989) · Chemical Reviews · doi:10.1021/cr00097a001 · Cited by 496
Cited by
Expanding the Scope of RAFT Polymerization: Recent Advances and New Horizons
Hill, M. R., Carmean, R. N., & Sumerlin, B. S. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00342 · Cited by 494
McKenzie, T. G., Fu, Q., Uchiyama, M., Satoh, K., Xu, J., Boyer, C., Kamigaito, M., & Qiao, G. G. (2016) · Advanced Science · doi:10.1002/advs.201500394 · Cited by 283
Self-citationThiocarbonyl chemistry in polymer science
Bingham, N. M., Abousalman-Rezvani, Z., Collins, K., & Roth, P. J. (2022) · Polymer Chemistry · doi:10.1039/d2py00050d · Cited by 66
Organocatalyst‐Catalyzed Non‐Radical Photopolymerizations
Liao, Y., & Liao, S. (2025) · Organocatalysts in Polymer Chemistry · doi:10.1002/9783527843077.ch13
Metadata
- Authors
- Uchiyama, M., Satoh, K., & Kamigaito, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-12-15
- Volume
- 54
- Issue
- 6
- Pages
- 1924-1928
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2105422659
- Cited by
- 211
- References
- 3
- FWCI
- 5.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- Uchiyama, M., Satoh, K., & Kamigaito, M. (2015). Cationic RAFT Polymerization Using ppm Concentrations of Organic Acid. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201410858
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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