Radical chemistry associated with the thiocarbonyl group
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRadical chemistry associated with the thiocarbonyl groupDavid Crich and Leticia QuinteroCite this: Chem. Rev. 1989, 89, 7, 1413–1432Publication Date (Print):November 1, 1989Publication History Published online1 May 2002Published inissue 1 November 1989https://pubs.acs.org/doi/10.1021/cr00097a001https://doi.org/10.1021/cr00097a001research-articleACS PublicationsRequest reuse permissionsArticle Views5495Altmetric-Citations430LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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Thiocarbonyl compounds are fundamentally useful in radical chemistry and are extensively utilized to produce various molecules and macromolecules in reactions such as the Barton-McCombie reaction and RAFT polymerization.
“Thiocarbonyl compounds are fundamentally useful in radical chemistry and are extensively utilized to produce various molecules and macromolecules in reactions such as the Barton–McCombie reaction and reversible addition–fragmentation chain transfer (RAFT) polymerization.1−4”
From Direct Radical Copolymerizations of Thioamides To Generate Vinyl Polymers with Degradable Thioether Bonds in the Backbones (2023) · cites this paper as [1]
β-Scission of the intermediate radical formed upon radical addition to the sulfur atom of the C=S double bond plays a vital role in reactions such as the Barton-McCombie reaction and RAFT polymerization.
“In these reactions, β-scission of the intermediate radical formed upon radical addition to the sulfur atom of the C=S double bond plays a vital role (Figure 1A).”
From Direct Radical Copolymerizations of Thioamides To Generate Vinyl Polymers with Degradable Thioether Bonds in the Backbones (2023) · cites this paper as [1]
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- Authors
- Crich, D., & Quintero, L.
- ORCID
- Crich, David
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 1989-11-01
- Volume
- 89
- Issue
- 7
- Pages
- 1413-1432
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2069285941
- Cited by
- 496
- References
- 0
- Citations by year
- 2026: 13 · 2025: 15 · 2024: 13 · 2023: 23 · 2022: 10 · 2021: 12 · 2020: 16 · 2019: 24 · 2018: 12 · 2017: 11 · 2016: 15 · 2015: 10 · 2014: 13 · 2013: 15 · 2012: 24
- FWCI
- 26.93
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemical Reviews (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Synthesis and Reactivity of Sulfur-Containing Compounds
- Physical Sciences › Chemistry › Organic Chemistry › Radical Photochemical Reactions
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Chemical Reactions and Mechanisms
- Keywords
- radical chemistry, thiocarbonyl group, sulfur-nitrogen heterocycles, radical reactivity
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