The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
Highly Efficient Ruthenium‐Catalyzed N‐Formylation of Amines with H2 and CO2
Abstract
A highly efficient catalyst system based on ruthenium‐pincer‐type complexes has been discovered for N‐formylation of various amines with CO 2 and H 2, thus affording the corresponding formamides with excellent productivity (turnover numbers of up to 1 940 000 in a single batch) and selectivity. Using a simple catalyst recycling protocol, the catalyst was reused for 12 runs in N,N‐dimethylformamide production without significant loss of activity, thus demonstrating the potential for practical utilization of this cost‐effective process. A one‐pot two‐step procedure for hydrogenation of CO 2 to methanol via the intermediacy of formamide formation has also been developed.
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Cites
Aresta, M., Dibenedetto, A., & Angelini, A. (2014) · Chemical Reviews · doi:10.1021/cr4002758 · Cited by 3,143
Weissermel, K., & Arpe, H. (1997) · Wiley eBooks · doi:10.1002/9783527616688 · Cited by 1,876
Homogeneous Hydrogenation of Carbon Dioxide
Jessop, P. G., Ikariya, T., & Noyori, R. (1995) · Chemical Reviews · doi:10.1021/cr00034a001 · Cited by 1,035
Bond Activation and Catalysis by Ruthenium Pincer Complexes
Gunanathan, C., & Milstein, D. (2014) · Chemical Reviews · doi:10.1021/cr5002782 · Cited by 958
Carbon Dioxide as a Raw Material: The Synthesis of Formic Acid and Its Derivatives from CO2
Leitner, W. (1995) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199522071 · Cited by 797
Recent advances in the homogeneous hydrogenation of carbon dioxide
Jessop, P. G., Joó, F., & Tai, C.-C. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.05.019 · Cited by 741
Jessop, P. G., Hsiao, Y., Ikariya, T., & Noyori, R. (1996) · Journal of the American Chemical Society · doi:10.1021/ja953097b · Cited by 610
Cascade Catalysis for the Homogeneous Hydrogenation of CO2to Methanol
Huff, C. A., & Sanford, M. S. (2011) · Journal of the American Chemical Society · doi:10.1021/ja208760j · Cited by 587
Federsel, C., Boddien, A., Jackstell, R., Jennerjahn, R., Dyson, P. J., Scopelliti, R., Laurenczy, G., & Beller, M. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201004263 · Cited by 542
Hydrogenation of Carbon Dioxide to Methanol by Using a Homogeneous Ruthenium–Phosphine Catalyst
Wesselbaum, S., vom Stein, T., Klankermayer, J., & Leitner, W. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201202320 · Cited by 540
Cited by
Klankermayer, J., Wesselbaum, S., Beydoun, K., & Leitner, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507458 · Cited by 856
Metadata
- Authors
- Zhang, L., Han, Z., Zhao, X., Wang, Z., & Ding, K.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-04-07
- Volume
- 54
- Issue
- 21
- Pages
- 6186-6189
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2166449173
- Cited by
- 357
- References
- 39
- FWCI
- 16.23
- Type
- journal article
- Language
- en
- Open access
- closed
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