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Carbon Dioxide as a Raw Material: The Synthesis of Formic Acid and Its Derivatives from CO2
Abstract
The use of carbon dioxide as a raw material for chemical syntheses is an ecologically and economically valuable extension to the carbon sources used at the present time. In order to convert the thermodynamically stable and comparatively unreactive CO 2 molecule into the desired product in an efficient manner, suitable reaction conditions and activation mechanisms must be found. The catalytic reduction of CO 2 to formic acid and its derivatives has been intensively studied in recent years. A number of new approaches to the synthesis of formic acid from CO 2 have reached such a state of knowledge that continuing development may well lead to industrial‐scale operation in the near future. This can to a large extent be attributed to the fruitful interaction between investigative work into reaction mechanisms and the development of new catalytic systems.
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Citations
Cites
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824
Cited by
Carbon capture and storage (CCS): the way forward
Bui, M., Adjiman, C. S., Bardow, A., Anthony, E. J., Boston, A., Brown, S., Fennell, P. S., Fuss, S., Galindo, A., Hackett, L. A., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02342a · Cited by 4,374
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Centi, G., Quadrelli, E. A., & Perathoner, S. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00056g · Cited by 1,257
Coates, G. W., & Moore, D. R. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460442 · Cited by 1,154
Klankermayer, J., Wesselbaum, S., Beydoun, K., & Leitner, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507458 · Cited by 856
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Metadata
- Authors
- Leitner, W.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1995-11-03
- Volume
- 34
- Issue
- 20
- Pages
- 2207-2221
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2105565769
- Cited by
- 797
- References
- 1
- FWCI
- 26.21
- Type
- journal article
- Language
- en
- Open access
- closed
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- Leitner, W. (1995). Carbon Dioxide as a Raw Material: The Synthesis of Formic Acid and Its Derivatives from CO2. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.199522071
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
