The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Dimeric [Mo2S12]2− Cluster: A Molecular Analogue of MoS2 Edges for Superior Hydrogen‐Evolution Electrocatalysis
Abstract
Proton reduction is one of the most fundamental and important reactions in nature. MoS 2 edges have been identified as the active sites for hydrogen evolution reaction (HER) electrocatalysis. Designing molecular mimics of MoS 2 edge sites is an attractive strategy to understand the underlying catalytic mechanism of different edge sites and improve their activities. Herein we report a dimeric molecular analogue [Mo 2 S 12]2−, as the smallest unit possessing both the terminal and bridging disulfide ligands. Our electrochemical tests show that [Mo 2 S 12]2− is a superior heterogeneous HER catalyst under acidic conditions. Computations suggest that the bridging disulfide ligand of [Mo 2 S 12]2− exhibits a hydrogen adsorption free energy near zero (−0.05 eV). This work helps shed light on the rational design of HER catalysts and biomimetics of hydrogen‐evolving enzymes.
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Citations
Cites
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
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MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
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Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
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Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
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Hydrogen evolution by a metal-free electrocatalyst
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High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS2) Micro- and Nanostructures
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Cited by
Liu, Y., Jiang, S., Li, S., Zhou, L., Li, Z., Li, J., & Shao, M. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.01.094 · Cited by 508
Deng, Y., Ting, L. R. L., Neo, P. H. L., Zhang, Y.-J., Peterson, A. A., & Yeo, B. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b01848 · Cited by 270
Xie, M., Zhang, B., Jin, Z., Li, P., & Yu, G. (2022) · ACS Nano · doi:10.1021/acsnano.2c05190 · Cited by 167
Daeneke, T., Dahr, N., Atkin, P., Clark, R. M., Harrison, C. J., Brkljača, R., Pillai, N., Zhang, B. Y., Zavabeti, A., Ippolito, S. J., et al. (2017) · ACS Nano · doi:10.1021/acsnano.7b01632 · Cited by 77
Metadata
- Authors
- Huang, Z., Luo, W., Ma, L., Yu, M., Ren, X., He, M., Polen, S., Click, K., Garrett, B., Lu, J., Amine, K., Hadad, C., Chen, W., Asthagiri, A., & Wu, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-10-20
- Volume
- 54
- Issue
- 50
- Pages
- 15181-15185
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2144560751
- Cited by
- 190
- References
- 15
- FWCI
- 6.45
- Type
- journal article
- Language
- en
- Open access
- closed
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- Huang, Z., Luo, W., Ma, L., Yu, M., Ren, X., He, M., Polen, S., Click, K., Garrett, B., Lu, J., Amine, K., Hadad, C., Chen, W., Asthagiri, A., & Wu, Y. (2015). Dimeric [Mo2S12]2− Cluster: A Molecular Analogue of MoS2 Edges for Superior Hydrogen‐Evolution Electrocatalysis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201507529
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