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Solution‐Processed Two‐Dimensional MoS2 Nanosheets: Preparation, Hybridization, and Applications
Abstract
As one member of the emerging class of ultrathin two-dimensional (2D) transition-metal dichalcogenide (TMD) nanomaterials, the ultra-thin MoS2 nanosheet has attracted increasing research interest as a result of its unique structure and fascinating properties. Solution-phase methods are promising for the scalable production, functionalization, hybridization of MoS2 nanosheets, thus enabling the widespread exploration of MoS2 -based nanomaterials for various promising applications. In this Review, an overview of the recent progress of solution-processed MoS2 nanosheets is presented, with the emphasis on their synthetic strategies, functionalization, hybridization, properties, and applications. Finally, the challenges and opportunities in this research area will be proposed.
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“Among them, 2D CoP nanosheets are more feasible to enhance HER catalytic activity, since the 2D nanostructures enable to expose catalytically active sites which promote interfacial charge transfer.”
From Sub‐1.5 nm Ultrathin CoP Nanosheet Aerogel: Efficient Electrocatalyst for Hydrogen Evolution Reaction at All pH Values (2018) · cites this paper as [22]
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“MoS 2 nanosheets have been employed in additional investigations as a photothermal agent and drug carrier for antibacterial research [30,31], diagnostic imaging [32,33], and cancer treatment [27,28,32–34].”
High-Yield Exfoliated MXene Nanosheets through Vapor Energy-Driven Delamination
Shi, F., Han, C., Liu, P., Liang, E.-W., Zhang, L., Su, Z., & Lai, C. (2024) · ACS Applied Engineering Materials · doi:10.1021/acsaenm.4c00532 · Cited by 2
Chen, M.-T., Zhu, H., & Mitsuishi, M. (2023) · ACS Applied Nano Materials · doi:10.1021/acsanm.3c00108 · Cited by 2
Chen, Y., Chen, Z., Xiang, M.-H., Zhou, Y., & Zhang, J. (2023) · Journal of Materials Science: Materials in Electronics · doi:10.1007/s10854-022-09785-3 · Cited by 2
Toward layered MoS 2 anode for harvesting superior lithium storage
Zhang, Y., Ponnuru, H., Jiang, Q., Shan, H., Sari, H. M. K., Li, W., Wang, J., Hu, J., Peng, J., & Li, X. (2022) · RSC Advances · doi:10.1039/d1ra08255h · Cited by 7
Tang, K., Wang, G.-M., Ruan, Q.-D., Peng, F., Cao, H.-L., & Chu, P. (2020) · doi:10.1016/j.surfcoat.2020.126497 · Cited by 2
Liu, Y., Zhang, D., Zhang, K., Dong, W., Tian, C., & Mao, B. (2020) · Journal of Coordination Chemistry · doi:10.1080/00958972.2020.1843024 · Cited by 4
Iritani, K., Kaneko, K., Tahara, K., Feyter, S. D., & Tobe, Y. (2020) · ChemNanoMat · doi:10.1002/cnma.201900733 · Cited by 2
Size-dependent magnetism of patterned MoTe2 monolayer
Li, Y., Ma, Y.-Q., Feng, Z., Sun, Q., Li, R., Tang, Y., & Dai, X.-Q. (2020) · Materials Research Express · doi:10.1088/2053-1591/ab6191 · Cited by 2
Lin, Y., Wu, C.-Y., & Chang, H.-C. (2019) · Zhongguó wùli xuékan · doi:10.1016/j.cjph.2019.07.005 · Cited by 2
Bento, R. T. (2026) · Materials Chemistry and Physics · doi:10.1016/j.matchemphys.2026.132639 · Cited by 1
Lee, S.-C., Choi, E., Kim, J., Park, S., Pyo, C., Lee, D., Kang, J., Shin, W., & Kim, M. (2026) · Sensors and actuators. B, Chemical · doi:10.1016/j.snb.2026.139540 · Cited by 1
Singh, G., Joshi, A. J., Adarsh, T., Swami, S., Veerababu, N., Materny, A., & Singh, D. K. (2026) · Synthetic Metals · doi:10.1016/j.synthmet.2026.118124 · Cited by 3
Alhussain, H., Toghan, A., Roushdy, N., Al-Hussain, S. A., Mostafa, A. M., Masoud, E. M., Farag, A., & Elessawy, N. A. (2026) · RSC Advances · doi:10.1039/d5ra08356g · Cited by 1
Chen, X.-Y., Zhao, Y., Liu, Z.-H., Pang, Y.-T., Wei, D.-G., Wang, C.-J.-Y., & Yao, C.-B. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.169930 · Cited by 1
Bilayer Mos2 Based Memristive Crossbar Array for Neuromorphic Applications
Yadav, S., Patel, C., Chaudhary, S., Paul, A., Ghodke, S., & Mukherjee, S. (2024) · 2024 IEEE 24th International Conference on Nanotechnology (NANO) · doi:10.1109/nano61778.2024.10628597 · Cited by 1
“MoS 2 , a 2D nanomaterial, is highly regarded for its exceptional electronic properties, like adjustable bandgap and abundant carriers [10,11].”
BackgroundSouri, Z., Adeli, M., & Mehdipour, E. (2020) · doi:10.1039/d0nj03285a · Cited by 1
State‐of‐the‐Art and Perspective of Layered Materials
Munir, T., Kashif, M., Shahzad, A., Nasir, N., Imran, M., Anjum, N., & Mahmood, A. (2020) · doi:10.1002/9781119655190.ch15 · Cited by 1
Photocatalytic properties of MoS2 nanoflakes vertically assembled on reduced graphene oxide
Li, H., Li, W., Yang, H. Y., Li, W., Yuan, Z., Chen, M., Bittencourt, C., & Snyders, R. (2018) · Thin Solid Films · doi:10.1016/j.tsf.2018.12.020 · Cited by 1
Electronic and equilibrium properties of molybdenum disulphide: Density Functional Theory study
Kekana, M., Mahladisa, M., Matshaba, M., Sikhwivhilu, L., Ntsendwana, B., & Mosuang, T. (2024) · MATEC Web of Conferences · doi:10.1051/matecconf/202440602004 · Cited by 1
Han, M., & Yu, J. (2021) · E3S Web of Conferences · doi:10.1051/e3sconf/202124503019
Transition metal dichalcogenides for biomedical applications
Dutta, R. R., Devi, R., Dutta, H. S., & Gogoi, S. (2020) · Elsevier eBooks · doi:10.1016/b978-0-12-817650-4.00007-3 · Cited by 12
Ramakrishnan, K., Manoharan, I. S. K., Kumar, A., & Saravanan, M. (2026) · Ionics · doi:10.1007/s11581-026-07535-7
Ramachandran, H., & Nageswaran, S. (2026) · Frontiers in Nanotechnology · doi:10.3389/fnano.2026.1906127
Kaviani, M. M., Wang, H.-B., Allafchian, A., Karbasi, M., Davar, F., Li, Z.-L., & Estarki, M. (2026) · Results in Chemistry · doi:10.1016/j.rechem.2026.104008
Martha, S., & Parida, K. M. (2026) · RSC Advances · doi:10.1039/d6ra02803a
Yang, J.-B., Huang, Y.-T., Huang, Z.-S., Ni, I.-C., Chen, M.-H., & Wu, C.-I. (2026) · ACS Applied Electronic Materials · doi:10.1021/acsaelm.6c00940
General Oxidative Chemical Activation of Neutral Exciton Emission in Colloidal MoS2 Monolayers.
Li, C., Li, H.-Y., Zhang, C.-Y., Zhou, B.-X., Yan, X.-X., Tang, R.-N., Yi, L.-Z., He, Y.-X., Hsiao, T.-J., Wang, H., et al. (2026) · Journal of the American Chemical Society · doi:10.1021/jacs.6c07304
Sayago, I. I., Santos, J. P., Sánchez, C., Ogilvie, S. P., Dalton, A. Β., Muñoz, E., & Garriga, R. (2026) · Talanta · doi:10.1016/j.talanta.2026.130365
Pashynska, V. A., Kosevich, M., Stepanian, S., Boryak, O., Kuzema, P., Adamowicz, L., & Karachevtsev, V. (2026) · Low temperature physics (Woodbury, N.Y., Print) · doi:10.1063/10.0043373
Tuning Localized Excitonic States in TEA+‐Intercalated MoS2 for Near‐Field Enhancement
Li, J., Feng, H., Jiao, K.-K., Shui, Q., Shi, X.-Q., Weng, S.-R., Zhang, C.-J., & Yang, L.-B. (2026) · Laser & Photonics Reviews · doi:10.1002/lpor.202503266
Abbas, A., Mortazavi, S., Reyhani, A., Almaamori, M., & Khanlary, M. R. (2026) · Microsystem Technologies · doi:10.1007/s00542-026-06051-y
Multi-shelled nano-spheres in biosensing: classification, synthesis and applications
Srivastava, N., Singh, A., & Chattopadhyay, J. (2026) · International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde) · doi:10.1515/ijmr-2024-0230 · Cited by 1
“103 The MoS 2 FET biosensor exhibited a strong a ffi nity for the physisorption of PSA antibodies, allowing it to detect changes in on/o ff -current levels when PSA interacts with anti-PSA antibodies.”
Impact of interlayer distance on the electronic properties of WS₂/WSe₂ semiconducting heterobilayer
Salem, E. B., & Triki, M. (2026) · Journal of Physics: Condensed Matter · doi:10.1088/1361-648x/ae3cf3
“One of the most striking examples of layer number dependent behavior is the transition from an indirect band gap for the bulk crystal (3D) to a direct band gap in the quasi-2D mono-layer limit [4–6], occurring at the two in-equivalent K and K’ valleys of the Brillouin zone.”
Control of 2D Crystal Monodispersity through a Seeded Growth Approach
Zhang, Z., Hanrahan, P. D., Dziobek-Garrett, R., Ambrozaite, O., & Kempa, T. (2025) · ACS Applied Nano Materials · doi:10.1021/acsanm.5c05455
Zhang, X., Ge, J.-J., Xiao, W.-J., Bi, J.-S., Zhou, X., Aierken, A., Wang, G., Wang, D.-G., Chen, X., Liu, M.-Q., et al. (2025) · Physica. B, Condensed matter · doi:10.1016/j.physb.2025.417954
Self-citationElectrochemical Modulation of MoS 2 Structures to Boost Hydrogen Evolution Reaction Efficiency
Reddy, V. M., Marepally, B. C., Selvam, R., Saravanan, G., Maiyalagan, T., & Selvakumar, D. (2025) · Electroanalysis · doi:10.1002/elan.12046
Hasmin, H. F., Djajasuminta, L. I., Dwiputra, M. A., Emrinaldi, T., Roza, L., Umar, A. A., Ginting, R. T., & Fauzia, V. (2025) · Environmental Progress & Sustainable Energy · doi:10.1002/ep.14577
“23,24 On other hand, the top-down route is also feasible, namely liquid-phase exfoliation (LPE) to cleave bulk MoS 2 into nanosheets.”
Design of self-driven position-sensitive detector based on PtTe2/N-Si heterojunction
Xing, S., Du, R., Chen, L.-L. H., Lin, H.-W., & Tao, L. (2023) · Other Conferences · doi:10.1117/12.2686816
Photocatalytic and Photoelectrochemical Nitrogen Fixation
Shi, L., & Sun, H. (2021) · Wiley eBooks · doi:10.1002/9783527825073.ch11 · Cited by 1
Recent progress on laser illuminating 2D materials
Shan, G., Qin, R.-Z., Tan, H.-Y., Meng, Q., Li, J.-B., Hu, M., & Chen, H.-L. (2019) · Applied Optics and Photonics China · doi:10.1117/12.2548095
Synthèse de catalyseurs d'hydrotraitement structurés à l'aide de polymères
Hétier, V. (2019) · theses.fr (ABES) · doi:10.70675/ee5424f4z0d4ez4b7dzbbe3zee654393c836
MoS2 Nanosheets Encapsulated in Carbon Nanofibers as Binder-free Anode for Superior Lithium Storage
Deng, Y., Zhan, L., Wang, Y.-L., & Yang, S.-B. (2016) · doi:10.20944/preprints201612.0133.v1
“To overcome these shortcomings, researchers focus on fabricating single-layer or few layered MoS2 by chemical vapor deposition[11,12], chemical exfoliation[13] and mechanical exfoliation [14,15].”
BackgroundMoS2 Based Nanocomposites for Treatment of Industrial Effluents
Kaur, M., Krishnan, U., & Kumar, A. (2021) · doi:10.1007/978-3-030-68976-6_4
Metadata
- Authors
- Zhang, X., Lai, Z., Tan, C., & Zhang, H.
- Affiliations
- Nanyang Technological University (SG)
- Corresponding author
- Zhang, Hua
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-06-22
- Volume
- 55
- Issue
- 31
- Pages
- 8816-8838
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2468394572
- Cited by
- 678
- References
- 0
- Citations by year
- 2026: 30 · 2025: 45 · 2024: 47 · 2023: 51 · 2022: 56 · 2021: 57 · 2020: 78 · 2019: 94 · 2018: 101 · 2017: 102 · 2016: 16
- FWCI
- 4.15
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- MOE (MOE2013-T2-1-034, MOE2014-T2-2-093)
- NTU (M4081296.070.500000, M4081458.070.500000)
- Singapore Millennium Foundation
- National Research Foundation, Prime Minister's Office, Singapore
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
- Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Transition Metal Oxide Nanomaterials
- Keywords
- MoS2 nanosheets, two-dimensional materials, transition metal dichalcogenides, solution processing, scalable synthesis, functionalization, hybrid nanostructures, ultrathin nanosheets
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