Defect‐Rich MoS 2 Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution

Xie, Junfeng; Zhang, Hao; Li, Shuang; Wang, Ruoxing; Sun, Xu; Zhou, Min; Zhou, Jingfang; Lou, Xiong Wen (David); Xie, Yi

doi:10.1002/adma.201302685

Cited by 3,079Electrocatalysts for Energy Conversion2D Materials and ApplicationsFuel Cells and Related Materials

Defect‐Rich MoS 2 Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution

Xie, Junfeng, Zhang, Hao, Li, Shuang, Wang, Ruoxing, Sun, Xu, Zhou, Min, Zhou, Jingfang, Lou, Xiong Wen (David) +1 more·2013·Advanced Materials

DOI 10.1002/adma.201302685

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Abstract

Defect-rich MoS2 ultrathin nanosheets are synthesized on a gram scale for electrocatalytic hydrogen evolution. The novel defect-rich structure introduces additional active edge sites into the MoS2 ultrathin nanosheets, which significantly improves their electrocatalytic performance. Low onset overpotential and small Tafel slope, along with large cathodic current density and excellent durability, are all achieved for the novel hydrogen-evolution-reaction electrocatalyst.

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MWNTs aerogel support is beneficial for deposition and formation of MoSx nanoparticles and provides good distribution for the exposed active surface of MoSx nanoparticles.
“Therefore, MWNTs aerogel support would be beneficial for the deposition and formation of MoSx nanoparticles [27], and provide a good distribution for the exposed active surface of MoSx nanoparticles [28].”
From Three dimensional CNTs aerogel/MoSx as an electrocatalyst for hydrogen evolution reaction (2016) · cites this paper as [28]
TMDs as co-catalysts can improve photocatalytic activity because active S atoms on exposed edges of 2D MoS2 can strongly bond with H+ in solution, enabling H+ reduction to H2.
“Numerous reports have demonstrated that TMDs as co-catalysts can improve the photocatalytic activity for two main reasons: i) the active S atoms on the exposed edges of 2D MoS 2 can strongly bond with H + in solution, enabling the H + reduction to H 2 . [ 20,24,40,50,111,112 ] In this way, the photocatalytic activity for HER can be greatly enhanced.”
From 2D Transition‐Metal‐Dichalcogenide‐Nanosheet‐Based Composites for Photocatalytic and Electrocatalytic Hydrogen Evolution Reactions (2016) · cites this paper as [20]
The overpotential and Tafel slope of MoS2QD-aerogel-100 constitute the best catalytic activity reported for pure semiconducting-type MoS2 electrocatalysts up to the present.
“which is the best result for pure semiconducting type MoS2 electrocatalysts up until the present.”
From Highly Efficient Hydrogen Evolution from Seawater by Biofunctionalized Exfoliated MoS2 Quantum Dot Aerogel Electrocatalysts That Is Superior to Pt (2019) · cites this paper as [44]
MoS2 can be a promising electrocatalyst for HER.
“Recently, researchers have found that MoS2 can be a promising electrocatalyst for HER.22−31”
From In-Situ Growth of Few-Layered MoS2 Nanosheets on Highly Porous Carbon Aerogel as Advanced Electrocatalysts for Hydrogen Evolution Reaction (2015) · cites this paper as [28]

Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
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Authors: Xie, J., Zhang, H., Li, S., Wang, R., Sun, X., Zhou, M., Zhou, J., Lou, X. W. (., & Xie, Y.
Affiliations: University of Science and Technology of China (CN)
Hefei National Laboratory for Physical Sciences at the Microscale, Department of Chemistry University of Science and Technology of China Hefei Anhui 230026 P. R. China
University of South Australia (AU)
Nanyang Technological University (SG)
Corresponding author: Lou, Xiong Wen (David)
Xie, Yi
ORCID: Xie, Junfeng
Li, Shuang
Wang, Ruoxing
Sun, Xu
Zhou, Min
Zhou, Jingfang
Lou, Xiong Wen (David)
Xie, Yi
Venue: Advanced Materials
Publisher: Wiley
Published: 2013-08-13
Volume: 25
Issue: 40
Pages: 5807-5813
ISSN: 0935-9648 (ISSN-L)
1521-4095
DOI: 10.1002/adma.201302685
OpenAlex: W2078397056
Cited by: 3,079
References: 4
Citations by year: 2026: 115 · 2025: 126 · 2024: 154 · 2023: 194 · 2022: 252 · 2021: 250 · 2020: 322 · 2019: 377 · 2018: 362 · 2017: 327 · 2016: 281 · 2015: 202 · 2014: 111 · 2013: 5
FWCI: 72.49
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Advanced Materials (publishedVersion)
PubMed (publishedVersion)
Adelaide Research & Scholarship (AR&S) (University of Adelaide) (submittedVersion)
DR-NTU (Nanyang Technological University) (submittedVersion)
Funders: National Science Foundation
National Key Research and Development Program of China
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
Keywords: MoS2, MoS2 nanosheets, defect engineering, edge sites, electrocatalytic hydrogen evolution, ultrathin nanosheets, large-scale synthesis, overpotential, Tafel slope, catalyst stability
MeSH terms: Catalysis, Disulfides, Hydrogen, Molybdenum, Oxidation-Reduction, Nanostructures

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Defect‐Rich MoS 2 Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution

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