The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Molybdenum–Bismuth Bimetallic Chalcogenide Nanosheets for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Methanol
Abstract
Methanol is a very useful platform molecule and liquid fuel. Electrocatalytic reduction of CO 2 to methanol is a promising route, which currently suffers from low efficiency and poor selectivity. Herein we report the first work to use a Mo‐Bi bimetallic chalcogenide (BMC) as an electrocatalyst for CO 2 reduction. By using the Mo‐Bi BMC on carbon paper as the electrode and 1‐butyl‐3‐methylimidazolium tetrafluoroborate in MeCN as the electrolyte, the Faradaic efficiency of methanol could reach 71.2 % with a current density of 12.1 mA cm−2, which is much higher than the best result reported to date. The superior performance of the electrode resulted from the excellent synergistic effect of Mo and Bi for producing methanol. The reaction mechanism was proposed and the reason for the synergistic effect of Mo and Bi was discussed on the basis of some control experiments. This work opens a way to produce methanol efficiently by electrochemical reduction of CO 2.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
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Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
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Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst
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Carbon dioxide utilisation for production of transport fuels: process and economic analysis
Dimitriou, I., García-Gutiérrez, P., Elder, R. H., Cuéllar-Franca, R. M., Azapagic, A., & Allen, R. W. K. (2015) · Energy & Environmental Science · doi:10.1039/c4ee04117h · Cited by 301
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Fundamentals and challenges of electrochemical CO2 reduction using two-dimensional materials
Sun, Z., Ma, T., Tao, H., Fan, Q., & Han, B. (2017) · Chem · doi:10.1016/j.chempr.2017.09.009 · Cited by 1,224
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Metadata
- Authors
- Sun, X., Zhu, Q., Kang, X., Liu, H., Qian, Q., Zhang, Z., & Han, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-04-21
- Volume
- 55
- Issue
- 23
- Pages
- 6771-6775
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2339213565
- Cited by
- 274
- References
- 6
- FWCI
- 8.76
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sun, X., Zhu, Q., Kang, X., Liu, H., Qian, Q., Zhang, Z., & Han, B. (2016). Molybdenum–Bismuth Bimetallic Chalcogenide Nanosheets for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Methanol. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201603034
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