The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Organic‐Base‐Driven Intercalation and Delamination for the Production of Functionalized Titanium Carbide Nanosheets with Superior Photothermal Therapeutic Performance
Abstract
The delamination of titanium carbide sheets, an intriguing class of two‐dimensional materials, has been critically dependent on the extraction of interlayer Al in acidic media, such as concentrated hydrofluoric acid (HF) or a mixture of hydrochloric acid (HCl) and a fluoride salt. Herein, we report an organic‐base‐driven intercalation and delamination of titanium carbide that takes advantage of the amphoteric nature of interlayer Al. The resulting aluminum‐oxoanion‐functionalized titanium carbide sheets manifested unusually strong optical absorption in the near‐infrared (NIR) region with a mass extinction coefficient as high as 29.1 L g−1 cm−1 at 808 nm. Thus, the performance of this material is comparable or even superior to that of state‐of‐the‐art photoabsorption materials, including gold‐based nanostructures, carbon‐based materials, and transition‐metal dichalcogenides. Preliminary studies show that the titanium carbide sheets serve as efficient photothermal agents against tumor cells.
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Liu, Y., Ai, K., & Lu, L. (2014) · Chemical Reviews · doi:10.1021/cr400407a · Cited by 4,794
Cited by
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Li, T., Yao, L., Liu, Q., Gu, J., Luo, R., Li, J., Yan, X., Wang, W., Liu, P., Chen, B., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201800887 · Cited by 1,457
Recent Advances in Oxidation Stable Chemistry of 2D MXenes
Cao, F., Zhang, Y., Wang, H., Khan, K., Tareen, A. K., Qian, W., Zhang, H., & Ågren, H. (2022) · Advanced Materials · doi:10.1002/adma.202107554 · Cited by 648
Selective Etching of Silicon from Ti3SiC2 (MAX) To Obtain 2D Titanium Carbide (MXene)
Alhabeb, M., Maleski, K., Mathis, T. S., Sarycheva, A., Hatter, C. B., Uzun, S., Levitt, A., & Gogotsi, Y. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201802232 · Cited by 452
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Self-citationTwo-Dimensional Ti3C2 MXene for High-Resolution Neural Interfaces
Driscoll, N., Richardson, A. G., Maleski, K., Anasori, B., Adewole, O., Lelyukh, P., Escobedo, L., Cullen, D. K., Lucas, T. H., Gogotsi, Y., et al. (2018) · ACS Nano · doi:10.1021/acsnano.8b06014 · Cited by 312
Metadata
- Authors
- Xuan, J., Wang, Z., Chen, Y., Liang, D., Cheng, L., Yang, X., Liu, Z., Ma, R., Sasaki, T., & Geng, F.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-10-24
- Volume
- 55
- Issue
- 47
- Pages
- 14569-14574
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2538234896
- Cited by
- 595
- References
- 1
- FWCI
- 16.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xuan, J., Wang, Z., Chen, Y., Liang, D., Cheng, L., Yang, X., Liu, Z., Ma, R., Sasaki, T., & Geng, F. (2016). Organic‐Base‐Driven Intercalation and Delamination for the Production of Functionalized Titanium Carbide Nanosheets with Superior Photothermal Therapeutic Performance. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201606643
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