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Cited by 386

The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.

Solid‐State Emission of the Anthracene‐o‐Carborane Dyad from the Twisted‐Intramolecular Charge Transfer in the Crystalline State

Naito, Hirofumi, Nishino, Kenta, Morisaki, Yasuhiro, Tanaka, Kazuo, Chujo, Yoshiki·2017·Angewandte Chemie International Edition

Abstract

The emission process of the o‐carborane dyad with anthracene originating from the twisted intramolecular charge transfer (TICT) state in the crystalline state is described. The anthracene‐o‐carborane dyad was synthesized and its optical properties were investigated. Initially, the dyad had aggregation‐ and crystallization‐induced emission enhancement (AIEE and CIEE) properties via the intramolecular charge transfer (ICT) state. Interestingly, the dyad presented the dual‐emissions assigned to both locally excited (LE) and ICT states in solution. From the mechanistic studies and computer calculations, it was indicated that the emission band from the ICT should be attributable to the TICT emission. Surprisingly, even in the crystalline state, the TICT emission was observed. It was proposed from that the compact sphere shape of o‐carborane would allow for rotation even in the condensed state.

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Metadata

Authors
Naito, H., Nishino, K., Morisaki, Y., Tanaka, K., & Chujo, Y.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2016-12
Volume
56
Issue
1
Pages
254-259
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2558822712
Cited by
386
References
42
FWCI
20.08
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Solid‐State Emission of the Anthracene‐o‐Carborane Dyad from the Twisted‐Intramolecular Charge Transfer in the Crystalline State. https://app.cochat.ai/papers/10.1002/anie.201609656
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Naito, H., Nishino, K., Morisaki, Y., Tanaka, K., & Chujo, Y. (2017). Solid‐State Emission of the Anthracene‐o‐Carborane Dyad from the Twisted‐Intramolecular Charge Transfer in the Crystalline State. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201609656

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